A three-dimensional coordination polymer with an expanded NbO structure

被引：0
|
作者：
Niu, TY [1 ]
Wang, XQ [1 ]
Jacobson, AJ [1 ]
机构：
[1] Univ Houston, Dept Chem, Houston, TX 77204 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1999年 / 38卷 / 13-14期
关键词：
coordination polymers; nickel; solid-state structures; tin;
D O I：
10.1002/(SICI)1521-3773(19990712)38:13/14<1934::AID-ANIE1934>3.0.CO;2-N
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The connection of square-planar [Ni(CN)4]2- ions with Ph3Sn+ ions results in 1, a noninterpenetrated three-dimensional coordination polymer with an expanded NbO structure. The (Ph3Sn)2Ni(CN)4 framework (shown schematically without phenyl groups and solvent molecules) displays a large central cavity that is occupied by Ph3SnOH, acetonitrile, and water molecules.
引用
收藏
页码：1934 / 1937
页数：4
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