Gold on amine-functionalized magnetic nanoparticles: A novel and efficient catalyst for hydrogenation reactions

被引:38
|
作者
Zhang, Fengwei [1 ]
Liu, Na [1 ]
Zhao, Ping [1 ]
Sun, Jian [1 ]
Wang, Peng [1 ]
Ding, Wen [1 ]
Liu, Juntao [1 ]
Jin, Jun [1 ]
Ma, Jiantai [1 ]
机构
[1] Lanzhou Univ, State Key Lab Appl Organ Chem, Coll Chem & Chem Engn, Lanzhou 730000, Peoples R China
关键词
Magnetic nanoparticles; Gold nanoparticles; Polyethyleneimine; 4-Nitrophenol; Hydrogenation reactions; AEROBIC OXIDATION; ALCOHOLS; EPOXIDATION; METAL;
D O I
10.1016/j.apsusc.2012.09.084
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A facile method is presented for the immobilization of gold nanoparticles on polyethyleneimine functionalized magnetite. The catalyst was characterized by TEM, XRD, TGA, FT-IR, XPS and VSM. This catalyst afforded a fast conversion of the 4-nitrophenol to 4-aminophenol at the presence of NaBH4, and an excellent yield was still achieved after it was reused ten times. (C) 2012 Elsevier B. V. All rights reserved.
引用
收藏
页码:471 / 475
页数:5
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