Theoretical examination of optical and EPR spectra for Cu2+ ion in KRdCl4 crystal

被引：17

作者：

Huang, P ^{[1
]}

Ping, H ^{[1
]}

Zhao, MG ^{[1
]}

机构：

[1] Sichuan Normal Univ, Inst Solid State Phys, Dept Informat Sci, Chengdu 610068, Peoples R China

来源：

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS | 2003年 / 64卷 / 03期

关键词：

crystal and ligand field; electron paramagnetic resonance;

D O I：

10.1016/S0022-3697(02)00277-9

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this work, two d-d transition spectra and four EPR parameters g(parallel to), g(perpendicular to), A(parallel to), A(perpendicular to) of K2PdCl4/Cu2+ are uniformly interpreted based on Zhao's crystal-field model. The calculation result is in good agreement with the experiment findings. The ligand spin-orbit coupling is neglected on the calculation, which is consistent with the ab initio result by Hillier et al. [J. Am. Chem. Soc. 98 (1976)95] (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：523 / 525

页数：3

共 50 条

[21] EPR study of Cu2+ ion doped orotato(nicotinamid)cobalt(II) single crystal
Yildirim, I.
Karabulut, B.
Buyukgungor, O.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2016, 152 : 608 - 613
[22] EPR STUDY OF CU2+ ION DOPED IN POTASSIUM OXALATE MONOPERHYDRATE SINGLE-CRYSTAL
MAURYA, BP
PUNNOOSE, A
UMAR, M
SINGH, RJ
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1995, 51 (04): : 661 - 667
[23] DISPLAY OF PSEUDO-JAHN-TELLER EFFECT IN EPR-SPECTRA OF CU2+ ION IN ND4BR
SOROKIN, MV
CHIRKIN, GK
FIZIKA TVERDOGO TELA, 1979, 21 (10): : 2987 - 2993
[24] An EPR and optical absorption study of Cu2+ doped in disodium malonate trihydrate single crystal
Yarbasi, Zeynep
Karabulut, Buenyamin
Karabulut, Abdulhalik
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2009, 72 (02) : 366 - 368
[25] EPR and optical absorption studies of Cu2+ doped lithium maleate dihydrate single crystal
Kripal, Ram
Pandey, Shri Devi
PHYSICA B-CONDENSED MATTER, 2014, 444 : 14 - 20
[26] Theoretical investigation of optical and EPR spectra for nickel (II) in ANSH crystal
Feng, W. -L.
Chen, T. -H.
Wang, L. -J
Chen, J. -J
OPTIK, 2010, 121 (04): : 362 - 365
[27] EPR SPECTRA OF CU2+ AND MN2+ ADSORBED ON SURFACE OF SILICON
PETROVA, AG
RAKOV, AV
YARYGIN, VP
IVANOV, EN
PASHINTS.YI
SOVIET PHYSICS SEMICONDUCTORS-USSR, 1971, 5 (06): : 1002 - &
[28] EPR-SPECTRA OF CU2+ IN SINGLE-CRYSTALS OF CHABAZITE
CHAO, CC
LUNSFORD, JH
JOURNAL OF CHEMICAL PHYSICS, 1973, 59 (08): : 3920 - 3925
[29] ABSORPTION SPECTRA OF CU2+ IN DIFFERENT CRYSTAL COORDINATIONS
PAPPALARDO, R
JOURNAL OF MOLECULAR SPECTROSCOPY, 1961, 6 (06) : 554 - &
[30] Investigation of the EPR parameters of an orthorhombic Cu2+ center in Cs2ZnCl4 crystal
Dong, HN
Wu, SY
Liu, XR
Chen, WD
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES, 2005, 60 (05): : 373 - 375

← 1 2 3 4 5 →