Theoretical examination of optical and EPR spectra for Cu2+ ion in KRdCl4 crystal

被引：17

作者：

Huang, P ^{[1
]}

Ping, H ^{[1
]}

Zhao, MG ^{[1
]}

机构：

[1] Sichuan Normal Univ, Inst Solid State Phys, Dept Informat Sci, Chengdu 610068, Peoples R China

来源：

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS | 2003年 / 64卷 / 03期

关键词：

crystal and ligand field; electron paramagnetic resonance;

D O I：

10.1016/S0022-3697(02)00277-9

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this work, two d-d transition spectra and four EPR parameters g(parallel to), g(perpendicular to), A(parallel to), A(perpendicular to) of K2PdCl4/Cu2+ are uniformly interpreted based on Zhao's crystal-field model. The calculation result is in good agreement with the experiment findings. The ligand spin-orbit coupling is neglected on the calculation, which is consistent with the ab initio result by Hillier et al. [J. Am. Chem. Soc. 98 (1976)95] (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：523 / 525

页数：3

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