A Homochiral Microporous Hydrogen-Bonded Organic Framework for Highly Enantioselective Separation of Secondary Alcohols

被引：296
|
作者：
Li, Peng [1 ]
He, Yabing [1 ]
Guang, Jie [1 ]
Weng, Linghong [2 ]
Zhao, John Cong-Gui [1 ]
Xiang, Shengchang [3 ]
Chen, Banglin [1 ]
机构：
[1] Univ Texas San Antonio, Dept Chem, San Antonio, TX 78249 USA
[2] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China
[3] Fujian Normal Univ, Coll Chem & Mat, Fuzhou 350007, Peoples R China
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2014年 / 136卷 / 02期
关键词：
SELECTIVE SEPARATION; SMALL MOLECULES; NETWORK; CRYSTALS; RECOGNITION; CATALYSIS; BINDING;
D O I：
10.1021/ja4129795
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A homochiral microporous hydrogen. bonded organic framework (HOF-2) based on a BINOL derivative has been synthesized and structurally characterized to be a uninodal 6-connected {3(3)5(5)6(6)7} network. This new HOF exhibits not only a permanent porosity with the BET of 237.6 m(2) g(-1) but also, more importantly, a highly enantioselective separation of chiral secondary alcohols with ee value up to 92% for 1-phenylethanol.
引用
收藏
页码：547 / 549
页数：3
相关论文
共 50 条
  • [41] Porphyrin nanotubes based on a hydrogen-bonded organic framework
    Idrees, Sumra
    Li, Zhikai
    Fang, Fang
    He, Huowang
    Majeed, Irfan
    Zhang, Yihuan
    Osuka, Atsuhiro
    Cao, Yan
    Zeng, Zhuo
    Li, Xiaopeng
    Jiang, Hua-Wei
    NANOSCALE, 2022, 14 (39) : 14630 - 14635
  • [42] Microporous Cyclen-Based Octacarboxylate Hydrogen-Bonded Organic Framework Exhibiting Selective Gas Adsorption
    Stackhouse, Chavis
    Ren, Junyu
    Shan, Chuan
    Nafady, Ayman
    Al-Enizi, Abdullah M.
    Ubaidullah, Mohd
    Niu, Zheng
    Ma, Shengqian
    CRYSTAL GROWTH & DESIGN, 2019, 19 (11) : 6377 - 6380
  • [43] A Hydrogen-Bonded Organic Framework Equipped with a Molecular Nanovalve
    Ghazal, Sara A.
    Tabbalat, Sarah W.
    Gandara, Felipe
    Al-Ghourani, Ala'a
    Abusulieh, Samah M.
    Abdellatief, Mahmoud
    Sunoqrot, Suhair
    Cordova, Kyle E.
    ACS APPLIED MATERIALS & INTERFACES, 2024, 16 (13) : 16522 - 16531
  • [44] Multifunctional porous hydrogen-bonded organic framework materials
    Lin, Rui-Biao
    He, Yabing
    Li, Peng
    Wang, Hailong
    Zhou, Wei
    Chen, Banglin
    CHEMICAL SOCIETY REVIEWS, 2019, 48 (05) : 1362 - 1389
  • [45] Enzyme Encapsulation in a Porous Hydrogen-Bonded Organic Framework
    Liang, Weibin
    Carraro, Francesco
    Solomon, Marcello B.
    Bell, Stephen G.
    Amenitsch, Heinz
    Sumby, Christopher J.
    White, Nicholas G.
    Falcaro, Paolo
    Doonan, Christian J.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2019, 141 (36) : 14298 - 14305
  • [46] Exploring Multifunctional Hydrogen-Bonded Organic Framework Materials
    Zhang, Zhangjing
    Ye, Yingxiang
    Xiang, Shengchang
    Chen, Banglin
    ACCOUNTS OF CHEMICAL RESEARCH, 2022, 55 (24) : 3752 - 3766
  • [47] Preparation and applications of Hydrogen-Bonded organic framework membranes
    Deng, Wei-Hua
    Wang, Xue
    Xiao, Ke
    Li, Yunbin
    Liu, Chulong
    Yao, Zizhu
    Wang, Lihua
    Cheng, Zhibin
    Lv, Yuanchao
    Xiang, Shengchang
    Zhang, Zhangjing
    CHEMICAL ENGINEERING JOURNAL, 2024, 497
  • [48] A microporous six-fold interpenetrated hydrogen-bonded organic framework for highly selective separation of C2H4/C2H6
    Li, Peng
    He, Yabing
    Arman, Hadi D.
    Krishna, Rajamani
    Wang, Hailong
    Weng, Linhong
    Chen, Banglin
    CHEMICAL COMMUNICATIONS, 2014, 50 (86) : 13081 - 13084
  • [49] Binary Solvent Regulated Architecture of Ultra-Microporous Hydrogen-Bonded Organic Frameworks with Tunable Polarization for Highly-Selective Gas Separation
    Ding, Xiaojun
    Liu, Zeyu
    Zhang, Yusheng
    Ye, Gang
    Jia, Jianfeng
    Chen, Jing
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2022, 61 (13)
  • [50] A CHARGE-ASSISTED HYDROGEN-BONDED ORGANIC FRAMEWORK FOR SELECTIVE SEPARATION OF p-XYLENE
    Shi, Chundiao
    Li, Ziling
    Xiang, Shengchang
    Liu, Chulong
    Zheng, Ximing
    QUIMICA NOVA, 2024, 47 (05):
12345