Nonfullerene acceptors with a novel nonacyclic core for high-performance polymer solar cells

被引:6
|
作者
Hou, Ran [1 ]
Li, Miao [1 ]
Wang, Junkai [1 ]
Bi, Zhaozhao [2 ]
Feng, Shiyu [1 ]
Xu, Xinjun [1 ]
Ma, Wei [2 ]
Bo, Zhishan [1 ]
机构
[1] Beijing Normal Univ, Coll Chem, Key Lab Energy Convers & Storage Mat, Beijing 100875, Peoples R China
[2] Xi An Jiao Tong Univ, State Key Lab Mech Behav Mat, Xian 710049, Shaanxi, Peoples R China
关键词
RING ELECTRON-ACCEPTOR; EFFICIENCY; SOLUBILITY; MORPHOLOGY; EXTENSION; DESIGN;
D O I
10.1039/c8tc06245e
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We developed two new fused-ring electron acceptors (FREAs) (IDIDTT and IDIDTT-2F) with a nonacyclic core, which bears eight side chains. The rigid coplanar nonacyclic core structure could broaden the absorption to the near-infrared (NIR) region, reduce the nonradiative energy loss, and enhance the charge transport. Pairing with PBDB-T, polymer solar cells were fabricated and investigated. IDIDTT-2F-based optimized devices showed a power conversion efficiency (PCE) of 11.29% with a V-oc of 0.92 V, J(sc) of 19.79 mA cm(-2), and FF of 61.85%. Our results showed that FREAs with the nonacyclic core could be promising in achieving high performance polymer solar cells.
引用
收藏
页码:3335 / 3341
页数:7
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