Copolymerization with depropagation: Experiments and prediction of kinetics and properties of alpha-methylstyrene methyl methacrylate copolymers .1. Solution copolymerization

被引：0

作者：

Martinet, F

Guillot, J

机构：

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 1997年 / 65卷 / 12期

关键词：

alpha-methylstyrene; methyl methacrylate; equilibrium of propagation; ceiling temperature; kinetics; molecular weights; copolymer composition; glass transition temperature; software calculations;

D O I：

10.1002/(SICI)1097-4628(19970919)65:12<2297::AID-APP5>3.3.CO;2-A

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

alpha-Methylstyrene (alpha-MSt) and methyl methacrylate were copolymerized at 60 degrees C in toluene by radical polymerization induced by azobisisobutyronitrile. The kinetics were followed by gravimetry and correlated with the molecular weights, microstructure, and glass transition temperature. A model was developed taking into account the equilibrium of the alpha-MSt homopolymerization that could not be neglected at 60 degrees C and higher temperatures. The model is in good agreement with all the experimental data. (C) 1997 John Wiley & Sons, Inc.

引用

页码：2297 / 2313

页数：17

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