Tris(2,2′-bipyridine-κ2N:N′)cobalt(III) trichloride tetrahydrate

被引：16

作者：

Liu, Wen ^{[1
]}

Xu, Wei ^{[1
]}

Lin, Jian-Li ^{[1
]}

Xie, Hong-Zhen ^{[1
]}

机构：

[1] Ningbo Univ, Fac Mat Sci & Chem Engn, State Key Lab Base Novel Funct Mat & Preparat Sci, Ningbo 315211, Zhejiang, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷

关键词：

D O I：

10.1107/S1600536808038154

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, [Co(C10H8N2)(3)]Cl-3 center dot 4H(2)O, contains discrete [Co(bpy)(3)](3+) cations (bpy is 2,2'-bipyridine), Cl- anions and water molecules. The [Co(bpy)(3)](3+) complex cation exhibits C-2 symmetry with the twofold axis through the central Co atom and bisecting one bpy ligand and one of the Cl- anions. The four solvent water molecules and the remaining two Cl- anions lie on a mirror plane. Hydrogen-bond interactions define a two-dimensional layer structure parallel to (100), which consists of seven-membered [Cl-2(H2O)(5)], eight-membered [Cl-4(H2O)(4)] and ten-membered [Cl-2(H2O)(8)] rings.

引用

页码：M1586 / U987

页数：13

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