Four interpenetrating three-dimensional frameworks in the hydrogen-bonded structure of 5-hydroxyisophthalic acid-4,4′-trimethylenedipyridine (1/1)

被引:11
|
作者
Wheatley, PS [1 ]
Lough, AJ
Ferguson, G
Glidewell, C
机构
[1] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland
[2] Univ Toronto, Lash Miller Chem Labs, Toronto, ON M5S 3H6, Canada
关键词
D O I
10.1107/S0108270199006356
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The 1:1 adduct of 5-hydroxyisophthalie acid and 4,4'-trimethylenedipyridine is a salt, [HNC5H4(CH2)(3)C5H4N](+).[HOC6H3(COOH)COO](-) (C13H15N2+. C8H5O5-). The anions are linked into C(7) chains by means of O-H ... O hydrogen bonds [O ... O 2.734 (2) Angstrom and O-H ... O 176 degrees], and these chains are linked by the cations via O-H ... N and N-H ... O hydrogen bonds [O ... N 2.620(2) Angstrom, O-H ... N 175 degrees, N ... O 2.748(2) Angstrom and N-H ... O 176 degrees] into four identical but independent interpenetrating three-dimensional frameworks.
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页码:1486 / 1489
页数:4
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