Photodegradation of Rhodamine B over a novel photocatalyst of feather keratin decorated CdS under visible light irradiation

被引:37
|
作者
Wang, Qizhao [1 ]
Lian, Juhong [1 ]
Ma, Qiong [1 ]
Bai, Yan [1 ]
Tong, Jinhui [1 ]
Zhong, Junbo [2 ]
Wang, Rongmin [1 ]
Huang, Haohao [3 ]
Su, Bitao [1 ]
机构
[1] Northwest Normal Univ, Minist Educ China, Key Lab Ecoenvironm Related Polymer Mat, Coll Chem & Chem Engn, Lanzhou 730070, Peoples R China
[2] Sichuan Univ Sci & Engn, Coll Chem & Pharmaceut Engn, Key Lab Green Catalysis Sichuan Inst, High Educ Inst Sichuan, Zigong 643000, Peoples R China
[3] S China Univ Technol, Coll Mat Sci & Engn, Guangzhou 510640, Guangdong, Peoples R China
基金
中国国家自然科学基金;
关键词
HYDROGEN-PRODUCTION; COMPOSITE; TIO2; HETEROSTRUCTURES; DEGRADATION; PERFORMANCE; ARRAYS; FILMS; DYE;
D O I
10.1039/c5nj00987a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel photocatalyst of feather keratin (FK)-decorated CdS was synthesized by a simple co-precipitation method. Scanning electron microscopy (SEM) showed that the particle sizes of FK/CdS nanocomposites were smaller than pure CdS. The coexistence of FK and CdS in the photocatalysts was further confirmed by Fourier transform infrared (FT-IR) spectroscopy and X-ray photoelectron spectroscopy (XPS). The results of photocatalytic experiments demonstrated that the FK/CdS composites exhibit significantly enhanced photocatalytic activity for the photocatalytic degradation of RhB compared with pure CdS under visible light irradiation. The enhanced photocatalytic activity of the FK/CdS composites can be attributed to the similar affinity between FK and RhB, which can effectively separate the photogenerated electron-hole pairs. This method not only improves the photocatalytic activity of CdS, but also reduces the environmental pollution of waste feathers. In addition, the possible degradation mechanism of RhB is proposed.
引用
收藏
页码:7112 / 7119
页数:8
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