Design of enzyme-like complexing polymer sorbents and metal-polymer complex catalysts with memory to substrates

被引：0
|
作者：
Efendiev, A [1 ]
机构：
[1] Azerbaijan Natl Acad Sci, Inst Polymer Mat, Sumgait 5004, Azerbaijan
来源：
MACROMOLECULAR SYMPOSIA | 2006年 / 235卷
关键词：
catalysts; complex; enzymes; polymer; sorbent;
D O I：
10.1002/masy.200650312
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A new principle of design of enzyme-like complexing polymer sorbents and metal polymer complex catalysts has been developed. The principle is based on the use of memory of polymer composition and consists in conformational prearrangement of macromolecules of noncrosslinked complexing polymer favorable for sorbing metal ions and/or catalyzing substrate position followed by intermolecular crosslinking. it has been shown that prearranged polymer sorbents and catalysts demonstrate significantly improved sorption and catalytic properties.
引用
收藏
页码：89 / 97
页数：9
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