Synthesis and characteristics of novel fluorescence dyes based on chromeno[4,3,2-de][1,6]naphthyridine framework

被引：14

作者：

Wang, Haiying ^{[1
]}

Shi, Jingjing ^{[1
]}

Wang, Chao ^{[1
]}

Zhang, Xiaoxiao ^{[1
]}

Zhao, Lingling ^{[1
]}

Wan, Yu ^{[1
]}

Wu, Hui ^{[1
]}

机构：

[1] Jiangsu Normal Univ, Sch Chem & Chem Engn, Jiangsu Key Lab Green Synthet Funct Mat, Xuzhou 221116, Peoples R China

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 2013年 / 103卷

关键词：

Chromene; Naphthyridine; Carbazole; Chemical calculation; Electrochemical; Fluorescent; HOLE-TRANSPORTING MATERIALS; LIGHT-EMITTING-DIODES; ELECTROLUMINESCENT DEVICES; DERIVATIVES; POLYMERS; FLUORENE; EMITTERS; POTENT;

D O I：

10.1016/j.saa.2012.10.075

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

A series of entirely new framework chromeno[4,3,2-de][1,6]naphthyridine derivatives containing carbazole groups have been carefully designed and prepared. The relationship of photoluminescence property and structure of these compounds was systematically investigated via UV-vis, fluorescence and electrochemical analyzer. The HOMO and LUMO distributions of these compounds were calculated by density functional theory (DFT) (B3LYP; 6-31G*) method. These compounds exhibited high fluorescence quantum yields, desirable HOMO levels and high thermal stability, indicating that the combination of chromeno[4,3,2-de][1,6]naphthyridine and carbazole could be an efficient means to enhance hole-transporting ability and fluorescent quantum yield. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：62 / 67

页数：6

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