Hg(II).d8[M] Interactions: Are they Metallophilic Interactions or Spodium Bonds?

被引：5

作者：

Burguera, Sergi ^{[1
]}

Bauza, Antonio ^{[1
]}

Frontera, Antonio ^{[1
]}

机构：

[1] Univ Illes Balears, Dept Quim, Crta Valldemossa Km 7-5, Palma De Mallorca 07122, Baleares, Spain

来源：

CHEMPHYSCHEM | 2023年 / 24卷 / 24期

关键词：

DFT calculations; metallophilic; noncovalent interactions; spodium bonding; supramolecular chemistry; BASIS-SETS; CU; DENSITY; CENTERS; PROGRAM; AU; AG;

D O I：

10.1002/cphc.202300585

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Some literature reports have shown the existence of short Hg(II)...d(8)[M] (M=Pd, Pt) contacts between linear Hg(II) and square planar d(8)[M] complexes that have been defined as heterometallophilic interactions. Linear L-Hg(II)-L complexes exhibit a pi-hole or positive belt of electrostatic potential at the Hg atom, whereas late transition metals can serve as effective electron donors through their filled d(z)2 orbitals. This study provides compelling evidence that Hg(II)...d(8)[M] interactions should be more appropriately termed spodium bonds.

引用

页数：5

共 50 条

[11] Synthesis and characterization of dipyrazinylformamidine and its reactions with d8 M(II) halides (M = Pd and Pt)
Mash, Brandon
Haefner, Steven
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2016, 251
[12] Intermolecular metallophilic interactions in palladium(II) chalcogenolate compounds - An experimental and theoretical study
Cechin, Camila N.
Paz, Alisson, V
Piquini, Paulo C.
Bevilacqua, Andressa C.
Pineda, Nahum R.
Fagundes, Natalia, V
Abram, Ulrich
Lang, Ernesto S.
Tirloni, Barbara
POLYHEDRON, 2020, 177
[13] Modeling interactions of Hg(II) and bauxitic soils
Weerasooriya, Rohan
Tobschall, Heinz J.
Bandara, Atula
CHEMOSPHERE, 2007, 69 (10) : 1525 - 1532
[14] Thermodynamic assessment of Hg(II)-gibbsite interactions
Weerasooriya, Rohan
Seneviratne, Wasana
Kathriarachchi, Heasha A.
Tobschall, Heinz J.
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2006, 301 (02) : 452 - 460
[15] Cytotoxic hydrophilic iminophosphorane coordination compounds of d8 metals. Studies of their interactions with DNA and HSA
Carreira, Monica
Calvo-Sanjuan, Ruben
Sanau, Mercedes
Zhao, Xiangbo
Magliozzo, Richard S.
Marzo, Isabel
Contel, Maria
JOURNAL OF INORGANIC BIOCHEMISTRY, 2012, 116 : 204 - 214
[16] Agostic interactions in transition metal d8 complexes: Critical role of ancillary ligands on the strength of the bond
Pudasaini, Bimal
Janesko, Benjamin G.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 245
[17] A 3-D net based on weak metallophilic (Cu•••Cu) interactions
Zhou, Jian
Tan, Xiaofeng
Hu, Feilong
Zou, Hua-Hong
Almeida Paz, Filipe A.
Fu, Lianshe
Zhao, Rongqing
DALTON TRANSACTIONS, 2016, 45 (28) : 11292 - 11296
[18] Recent Advances in Phosphorescent Pt(II) Complexes Featuring Metallophilic Interactions: Properties and Applications
Aliprandi, Alessandro
Genovese, Damiano
Mauro, Matteo
De Cola, Luisa
CHEMISTRY LETTERS, 2015, 44 (09) : 1152 - 1169
[19] Metallophilic Interactions in Bimetallic Cyclometalated Platinum(II) N-Heterocyclic Carbene Complexes
Pinter, Piermaria
Soellner, Johannes
Strassner, Thomas
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2021, 2021 (30) : 3104 - 3107
[20] The importance of spodium bonds, H-bonds and π-stacking interactions in the solid state structures of four zinc complexes with tetradentate secondary diamine ligands
Middya, Puspendu
Karmakar, Mainak
Gomila, Rosa M.
Drew, Michael G. B.
Frontera, Antonio
Chattopadhyay, Shouvik
NEW JOURNAL OF CHEMISTRY, 2023, 47 (19) : 9346 - 9363

← 1 2 3 4 5 →