High entropy oxide catalysts with SO2 resistance in RWGS reaction

被引：4

作者：

Zhang, Mengyuan ^{[1
,2
]}

Lu, Xiaoyan ^{[1
]}

Luo, Kongliang ^{[1
]}

Ye, Jian ^{[1
]}

Dong, Jia li ^{[1
]}

Lu, Nana ^{[1
]}

Wang, Xiaopeng ^{[1
]}

Niu, Qiang ^{[3
]}

Zhang, Pengfei ^{[1
,2
]}

Dai, Sheng ^{[4
]}

机构：

[1] Ningxia Univ, Coll Chem & Chem Engn, State Key Lab High Efficiency Utilizat Coal & Gree, Yinchuan 750021, Peoples R China

[2] Shanghai Jiao Tong Univ, Sch Chem & Chem Engn, Shanghai 200240, Peoples R China

[3] Inner Mongolia Erdos Elect Power & Met Grp Co Ltd, Natl Enterprise Technol Ctr, Ordos 016064, Inner Mongolia, Peoples R China

[4] Oak Ridge Natl Lab, Chem Sci Div, Oak Ridge, TN 37830 USA

来源：

APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY | 2024年 / 349卷

关键词：

High entropy oxide; SO; 2; resistance; Entropy engineering; In situ FTIR; In situ XPS; RWGS reaction; REDUCTION; MECHANISM; NOX;

D O I：

10.1016/j.apcatb.2024.123845

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Ubiquitous presence of SO2 usually shows adverse effects on industrial catalysis. Herein, a concept of engineering entropy to design SO2 resistance oxide catalysts is proposed. (Ni0.2Mg0.2Cu0.2Zn0.2Co0.2)Fe2O4 showed excellent performance (the CO2 conv. = 41.4%, CO selec. = 99.6% at 400 degrees C) compared to the control samples in the reverse water-gas shift (RWGS). In addition, (Ni0.2Mg0.2Cu0.2Zn0.2Co0.2)Fe2O4 had the SO2-tolerant ability (the CO2 conv. = 38.5%, CO selec. = 99.2% at 400 degrees C) after being poisoned with 1000 ppm SO2 at 400 degrees C for 1 h. In sharp contrast, the control samples NiFe2O4, MgFe2O4, CuFe2O4 and CoFe2O4 lost their activity. O-1S XPS indicated that (Ni0.2Mg0.2Cu0.2Zn0.2Co0.2)Fe2O4 had higher oxygen vacancy concentrations. SO2 resistance mechanism was studied by infrared spectroscopy, SO2-TPD, in situ S 2p XPS and the DFT results, confirming that the low SO2 adsorption energy of (Ni0.2Mg0.2Cu0.2Zn0.2Co0.2)Fe2O4, which was attributed to the lower Gibbs free energy. This work may inspire the rational design of SO2-resistant catalysts.

引用

页数：12

共 50 条

[21] Adsorption and reaction of SO2 on model Ce1-xZrxO2(111) catalysts
Liu, G
Rodriguez, JA
Chang, ZP
Hrbek, J
Peden, CHF
JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (09): : 2931 - 2938
[22] Search for New Catalysts for the Oxidation of SO2
Loskyll, J.
Stoewe, K.
Maier, W. F.
ACS COMBINATORIAL SCIENCE, 2013, 15 (09) : 464 - 474
[23] ESTIMATE OF THE EFFICIENCY OF SO2 OXIDATION CATALYSTS
NEIMARK, AV
KHEIFETS, LI
SLINKO, MG
DOKLADY AKADEMII NAUK SSSR, 1979, 249 (01): : 123 - 127
[24] CHEMILUMINESCENCE IN THE REACTION OF DIPHENYLSULFENE WITH SO2
NAZAROV, AM
SERENKO, SY
KOMISSAROV, VD
TOLSTIKOV, GA
BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1990, 39 (11): : 2421 - 2421
[25] Catalysis mechanism in reduction of SO2 by CO over transition metal oxide catalysts
School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China
不详
不详
Tianjin Daxue Xuebao (Ziran Kexue yu Gongcheng Jishu Ban), 2006, 4 (391-395):
[26] Reaction of SO2 with Group IV and VI transition metal oxide clusters
Flores, Luis A.
Murphy, Julia G.
Copeland, William B.
Dixon, David A.
COMPUTATIONAL AND THEORETICAL CHEMISTRY, 2017, 1120 : 46 - 55
[27] Reaction of SO2 with OH in the atmosphere
Long, Bo
Bao, Junwei Lucas
Truhlar, Donald G.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2017, 19 (11) : 8091 - 8100
[28] MECHANISMS OF RESISTANCE TO SO2 IN CUCURBITACEAE
BRESSAN, RA
WILSON, LG
FILNER, P
PLANT PHYSIOLOGY, 1977, 59 (06) : 123 - 123
[29] Promotion Effect of Chromium on the Activity and SO2 Resistance of CeO2-TiO2 Catalysts for the NH3-SCR Reaction
Liu, Wuyuan
Gao, Zihan
Zhao, Xiangyun
Gao, Jiajian
Yang, Runnong
Yu, Lin
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2021, 60 (31) : 11676 - 11688
[30] PALLADIUM-CONTAINING AND COPPER-CHROME-OXIDE CATALYSTS IN THE REACTION OF CARBON OXIDE OXIDATION IN THE PRESENCE OF SO2 NOX H2O
MARTSENYUKKUKHARUK, MG
ORLIK, SN
KORNEICHUK, GP
PYATNITSKY, YI
UKRAINSKII KHIMICHESKII ZHURNAL, 1986, 52 (07): : 715 - 718

← 1 2 3 4 5 →