Pre-impregnation approach to encapsulate radioactive liquid organic waste in geopolymer

被引:5
|
作者
Mossini, Eros [1 ]
Santi, Andrea [1 ]
Magugliani, Gabriele [1 ]
Galluccio, Francesco [1 ]
Macerata, Elena [1 ]
Giola, Marco [1 ]
Vadivel, Dhanalakshmi [2 ]
Dondi, Daniele [2 ]
Cori, Davide [3 ]
Lotti, Paolo [4 ]
Gatta, Giacomo Diego [4 ]
Mariani, Mario [1 ]
机构
[1] Politecn Milan, Dept Energy, Piazza Leonardo da Vinci 32, I-20133 Milan, Italy
[2] Univ Pavia, Dept Chem, Via Taramelli 12, I-27100 Pavia, Italy
[3] Nucleco SpA, Via Anguillarese 301, I-00123 Rome, Italy
[4] Univ Milan, Dept Earth Sci, Via Sandro Botticelli 23, I-20133 Milan, Italy
关键词
Radioactive liquid organic waste; Recycled polyurethane; Pre-impregnation; Geopolymer; Waste acceptance criteria; SOLIDIFICATION-STABILIZATION; CEMENT; STABILIZATION/SOLIDIFICATION; DURABILITY; VISCOSITY; BEHAVIOR; MORTARS;
D O I
10.1016/j.jnucmat.2023.154608
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The pre-disposal management of Radioactive Liquid Organic Waste (RLOW) is hampered by its challenging physico-chemical properties. In this work, a straightforward conditioning option based on RLOW impregnation on absorbing materials and followed by encapsulation in a stable geopolymeric matrix is proposed, avoiding onerous pre-treatments and the use of surfactants. Recycled materials have been investigated as adsorbent and geopolymer precursors to foster process sustainability. Relevant properties have been studied to ascertain the waste acceptance criteria accomplishment: materials compatibility, RLOW loading factor and bleeding, microstructure, compressive strength, leaching and thermal stability. This approach is promising, although some criticalities remain unsolved.
引用
收藏
页数:9
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