Synthesis, Structure, and Optical Properties of a 0D Hybrid Organic-Inorganic Metal Halide (C5N2H14Cl)GeCl3

被引：5
|
作者：
Li, Yuchao [1 ,2 ]
He, Nan [1 ,2 ]
Xu, Bohui [1 ,2 ]
Dong, Linfeng [1 ,2 ]
Zhang, Xingyu [1 ,2 ]
Xu, Jing [4 ,5 ]
Gong, Pifu [1 ]
Lin, Zheshuai [1 ,3 ]
机构：
[1] Chinese Acad Sci, Tech Inst Phys & Chem, Funct Crystals Lab, Beijing 100190, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
[3] Univ Chinese Acad Sci, Ctr Mat Sci & Optoelect Engn, Beijing 100049, Peoples R China
[4] Renmin Univ China, Dept Phys, Beijing Key Lab Optoelect Funct Mat & Micronano De, Minist Educ, Beijing 100872, Peoples R China
[5] Renmin Univ China, Key Lab Quantum State Construction & Manipulat, Minist Educ, Beijing 100872, Peoples R China
来源：
INORGANIC CHEMISTRY | 2024年 / 63卷 / 09期
基金：
中国国家自然科学基金;
关键词：
WHITE-LIGHT EMISSION; BROAD-BAND EMISSION; PEROVSKITES;
D O I：
10.1021/acs.inorgchem.4c00091
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Due to the flexible structural tunability and excellent photoelectric performance, hybrid organic-inorganic metal halides (OIMHs) have attracted intensive attention and become a hot topic in the field of materials. It is important and necessary to explore new OIMHs and study their structure-property relationship. In this work, a new lead-free OIMH, (C5N2H14Cl)GeCl3, is synthesized by the combination of hydrothermal and solution methods. This compound features a zero-dimensional structure composed of inorganic [GeCl3](-) trigonal pyramids surrounded by isolated Cl- anions and organic (C5N2H14)(2+) cations. Preliminary characterization and first-principles calculations are performed to study its basic optical properties. Interestingly, (C5N2H14Cl)GeCl3 shows weak blue emission under ultraviolet excitation, and the intrinsic mechanism is discussed.
引用
收藏
页码：4412 / 4418
页数：7
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