Dynamic evolution of gas hydrate systems affected by magmatism and Quaternary mass-transport deposits in the Qiongdongnan Basin, South China Sea, and implications for the global carbon cycle

Methane release from hydrate systems has long been considered as one of the important mechanisms for global carbon cycle perturbations and ocean acidification. Here, a Quaternary active gas hydrate system in Qiong-dongnan Basin, South China Sea (SCS), has been analyzed by using seismic, logging while drilling (LWD), and core data. The results show that post-rift magmatism led to the reactivation of a magma diapir, and the faults and fractures related to its emplacement created efficient pathways for deep gas migration. The increase in over-burden temperature and circulation of deep thermal fluids, especially in the center of the diapir area, thinned the gas hydrate stability zone (GHSZ). The accumulation of natural gas at the base of GHSZ and the thinning of GHSZ decreased the ability of hydrate bearing sediments to seal free gas and lead to hydraulic fracturing. The free gas entering the GHSZ was buried by mass transport deposits (MTDs) and then formed hydrates due to the overlying compaction and so further sealed the free gas under the GHSZ. This study indicates that two contrasting mechanisms are acting: (1) tectonic activity and magmatism favor the release of deep natural gas which may reach the ocean, (2) MTDs and the overlying compacted sections act as seals, inhibiting the release of such gas to the ocean. This study shows how the seal capacity of MTDs may reduce methane release from deep-seated reservoirs into the ocean. Given their widespread distribution along continental margins, we suggest that the impact of MTDs on vertical fluid flow, and potential consequences for ocean chemistry and the global carbon cycle, might be underestimated.