Nuclear Dipole Moments and Shielding Constants of Light Nuclei Measured in Magnetic Fields

被引:3
|
作者
Makulski, Wlodzimierz [1 ]
Slowinski, Mateusz A. [1 ]
Garbacz, Piotr [1 ]
机构
[1] Univ Warsaw, Fac Chem, Lab NMR Spect, Pasteura 1, PL-02093 Warsaw, Poland
关键词
nuclear dipole moments; nuclear shielding constants; light nuclei; NMR spectroscopy; NMR-SPECTROSCOPY; COUPLED-CLUSTER; RESONANCE; HYDROGEN; HE-3; DEUTERON; PROTON; ISOTOPE; TRITON; TABLE;
D O I
10.3390/magnetochemistry9060148
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Nuclear magnetic resonance (NMR) is a branch of spectroscopy commonly used for identifying the chemical structure of various materials. One of the areas in which NMR provides accurate data is the determination of nuclear magnetic moments. This work reviews NMR experiments with the nuclei of light elements in simple molecules. Since nuclear shielding constants from up-to-date quantum calculations are now available, very accurate dipole moments of many nuclei can be determined. Recent experimental measurements of H-1, H-2, H-3, He-3, Li-6, Li-7, Be-9, B-10, and B-11 nuclear magnetic moments and the appropriate theoretical predictions are presented and commented upon. Several achievements in this field using different methodologies, such as NMR spectroscopy, molecular beam experiments, and the Penning trap method are reported.
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页数:16
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