Effect of highly oxidizing converter dephosphorization slag on dephosphorization behaviour of molten steel

被引:6
|
作者
Zhou, Chaogang [1 ,2 ]
Chen, Qinggong [1 ,3 ]
Ji, Yi [1 ]
Ai, Liqun [1 ,3 ]
Wang, Shuhuan [1 ,3 ,5 ,6 ]
Chen, Qiya [1 ,3 ]
Yuan, Tianxiang [4 ]
机构
[1] North China Univ Sci & Technol, Coll Met & Energy, Tangshan, Peoples R China
[2] Guizhou Minzu Univ, Coll Mat Sci & Engn, Guiyang, Peoples R China
[3] Tangshan Special Met & Mat Preparat Lab, Tangshan, Peoples R China
[4] Shougang Jingtang United Iron & Steel Co Ltd, Tangshan, Peoples R China
[5] North China Univ Sci & Technol, Coll Met & Energy, Tangshan 063210, Hebei, Peoples R China
[6] Tangshan Special Met & Mat Preparat Lab, Tangshan 063210, Hebei, Peoples R China
基金
中国国家自然科学基金;
关键词
High oxidative; dephosphorizing converter slag; duplex method; dephosphorization behaviour; slag structure; polymerization; FTIR; molten steel; FTIR SPECTRA; SILICATE-GLASSES; PHOSPHORUS; PHOSPHATE; CRYSTALLIZATION; SYSTEM; AL2O3; FE2O3; IRON; B2O3;
D O I
10.1080/03019233.2023.2168344
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
In order to study the effect of highly oxidizing dephosphorizing converter slag on the migration behaviour of phosphorus in molten steel, an industrial test was carried out on a 300t dephosphorizing converter in a steel plant by the duplex method. Theoretical analysis shows that when the temperature is low, the basicity is 1.5 and the FeO content is 25%-30%, the phosphorus capacity of slag is stable. The industrial test results show that when the temperature is 1630K-1665K, the basicity is 1.05-1.25, the FeO content is 35%-40%, and the dephosphorization efficiency of the converter can generally reach above 60%. XRD and SEM-EDS analysis results showed that phosphorus was mainly enriched in 2CaO center dot SiO2-3CaO center dot P2O5 solid solution. Infrared analysis results show that under the condition of high FeO and low basicity, properly increasing of basicity is beneficial to reduce the degree of polymerization of dephosphorization slag.
引用
收藏
页码:958 / 968
页数:11
相关论文
共 50 条
  • [11] Effect of Slag Phase on Dephosphorization in BOF
    Xia, Yunjin
    Wang, Duogang
    Wu, Liushun
    Li, Jie
    Fan, Dingdong
    ISIJ INTERNATIONAL, 2023, 63 (12) : 2086 - 2091
  • [12] Dephosphorization mechanism and phase change in the reduction of converter slag
    Xue, Yuekai
    Tian, Peng
    Li, Chenxiao
    Zhou, Chaogang
    Zhao, Dingguo
    Wang, Shuhuan
    HIGH TEMPERATURE MATERIALS AND PROCESSES, 2021, 40 (01) : 253 - 264
  • [13] Slag formation path during dephosphorization process in a converter
    Diao, Jiang
    Qiao, Yong
    Liu, Xuan
    Zhang, Xie
    Qiu, Xin
    Xie, Bing
    INTERNATIONAL JOURNAL OF MINERALS METALLURGY AND MATERIALS, 2015, 22 (12) : 1260 - 1265
  • [14] Slag formation path during dephosphorization process in a converter
    Jiang Diao
    Yong Qiao
    Xuan Liu
    Xie Zhang
    Xin Qiu
    Bing Xie
    International Journal of Minerals, Metallurgy, and Materials, 2015, 22 : 1260 - 1265
  • [15] Slag formation path during dephosphorization process in a converter
    Jiang Diao
    Yong Qiao
    Xuan Liu
    Xie Zhang
    Xin Qiu
    Bing Xie
    InternationalJournalofMineralsMetallurgyandMaterials, 2015, 22 (12) : 1260 - 1265
  • [16] Dephosphorization by Double-Slag Process in Converter Steelmaking
    Wang, Yang
    Yang, Shufeng
    Li, Jingshe
    Feng, Jie
    Wang, Feng
    HIGH TEMPERATURE MATERIALS AND PROCESSES, 2018, 37 (07) : 625 - 633
  • [17] EXPERIMENTAL RESEARCH OF CONVERTER DUST FOR MOLTEN IRON DEPHOSPHORIZATION
    Ren, Jian-hua
    Wu, Guang-liang
    7TH INTERNATIONAL SYMPOSIUM ON HIGH-TEMPERATURE METALLURGICAL PROCESSING, 2016, : 605 - 613
  • [18] DEPHOSPHORIZATION AND DESULFURIZATION OF MOLTEN STEEL BY A SODIUM FLORIDE FLUX
    ONO, H
    MASUI, T
    MORI, H
    TRANSACTIONS OF THE IRON AND STEEL INSTITUTE OF JAPAN, 1983, 23 (02) : B48 - B48
  • [19] The kinetics of dephosphorization of carbon-saturated iron using an oxidizing slag
    Monaghan, BJ
    Pomfret, RJ
    Coley, KS
    METALLURGICAL AND MATERIALS TRANSACTIONS B-PROCESS METALLURGY AND MATERIALS PROCESSING SCIENCE, 1998, 29 (01): : 111 - 118
  • [20] Microstructure and Viscosity of Dephosphorization Slag in New Double Slag Converter Steelmaking Process
    Yang, Wenkui
    Yang, Jian
    Zhang, Runhao
    Sun, Han
    ISIJ INTERNATIONAL, 2021, 61 (10) : 2490 - 2500