Energy-transfer sensitization of BODIPY fluorescence in a dyad with a two-photon absorbing antenna chromophore

被引:3
|
作者
Dominguez-Alfaro, Antonio [1 ]
Pais, Vania F. [1 ]
Guzman-Rios, David B. [1 ]
Collado, Daniel [2 ,3 ]
Najera, Francisco [2 ,3 ]
Perez-Inestrosa, Ezequiel [2 ]
Pischel, Uwe [1 ]
机构
[1] Univ Huelva, CIQSO Ctr Res Sustainable Chem, Campus Carmen S-N, E-21071 Huelva, Spain
[2] Univ Malaga, Fac Ciencias, Dept Quim Organ, E-29071 Malaga, Spain
[3] Inst Invest Biomed Malaga & Plataforma Nanomed IB, Plataforma Bionand, Parque Tecnol Andalucia, E-29590 Malaga, Spain
关键词
BODIPY dyes; Energy transfer; Electron transfer; Two -photon absorption; Bioimaging; HIGHLY FLUORESCENT; CHARGE SEPARATION; ELECTRON-TRANSFER; RATIONAL DESIGN; SINGLET OXYGEN; IN-VITRO; DYES; DYNAMICS; PROBES; MOLECULE;
D O I
10.1016/j.dyepig.2022.110950
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
A bichromophoric dyad composed of a Prodan-derived moiety and a BODIPY dye was prepared, photophysically characterized, and tested for multiphoton fluorescence microscopy of N13 microglial cells. The dyad shows highly efficient energy transfer, independent on the solvent polarity of the medium. However, in polar media photoinduced electron transfer is a competitive pathway. The Prodan-derived chromophore shows significant two-photon absorption. Hence, it can be used a two-photon-absorbing antenna for the sensitization of BODIPY fluorescence.
引用
收藏
页数:9
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