Degradation of Chemical Warfare Agent Nitrogen Mustard Using Ferrate (VI)

被引：3

作者：

Labaska, Miroslav ^{[1
]}

Gal, Miroslav ^{[2
]}

Mackulak, Tomas ^{[1
]}

机构：

[1] Slovak Univ Technol Bratislava, Fac Chem & Food Technol, Dept Environm Engn, Radlinskeho 9, Bratislava 81237, Slovakia

[2] Slovak Univ Technol Bratislava, Fac Chem & Food Technol, Dept Inorgan Technol, Radlinskeho 9, Bratislava 81237, Slovakia

来源：

TOXICS | 2023年 / 11卷 / 07期

关键词：

chemical warfare agent; decontamination; nitrogen mustard; ferrate (VI); SULFUR MUSTARD; NERVE AGENTS; DECONTAMINATION; DETOXIFICATION; OXIDATION; NANOPARTICLES; DESTRUCTION; KINETICS; OXIDES; OXYGEN;

D O I：

10.3390/toxics11070559

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Chemical warfare agents (CWAs) are one of the most toxic compounds. Degradation of CWAs using decontamination agents is one of the few ways to protect human health against the harmful effects of CWAs. A ferrate (VI)-based potential chemical warfare agent decontaminant was studied for the degradation of persistent nitrogen mustard (tris(2-chloroethyl)amine, HN3). By optimizing the reaction conditions, the complete degradation of HN3 was achieved in 4 min. The degradation products contained mostly reduced Fe species, which confirmed the environmental friendliness of the proposed decontamination solution.

引用

页数：8

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