Oxygen blocking enhancement of HfB2-SiC coating using HfB2-HfSi2 alloyed composite powders by self-propagating high-temperature synthesis

被引:3
|
作者
Shi, Dalin [1 ]
Ji, Xiang [2 ]
Wu, Binbin [1 ]
Ren, Xuanru [2 ]
Wang, Peipei [3 ]
Wang, Leyu [1 ]
Zhao, Yan [1 ]
Chen, Jiaping [1 ]
Yang, Chunmin [1 ]
Kiryukhantsev-Korneev, Philipp V. [4 ]
Levashov, Evgeny A. [4 ]
Shi, Ji [5 ]
Feng, Peizhong [1 ]
机构
[1] China Univ Min & Technol, Xuzhou 221116, Peoples R China
[2] Henan Acad Sci, Inst Carbon Matrix Composites, Henan Key Lab High Performance Carbon Fiber Reinfo, Zhengzhou 450046, Peoples R China
[3] Xian Univ Sci & Technol, Coll Mat Sci & Engn, Xian 710054, Shaanxi, Peoples R China
[4] Natl Univ Sci & Technol MISIS, Leninsky Prospect 4, Moscow 119049, Russia
[5] Tokyo Inst Technol, Sch Mat & Chem Technol, 2-12-1 Ookayama,Meguro Ku, Tokyo 1528552, Japan
关键词
HfSi; 2; HfB 2-SiC coating; Self-propagating high-temperature synthesis; Oxygen permeability; OXIDATION RESISTANCE; COMBUSTION SYNTHESIS; CERAMICS; BEHAVIOR; HFSI2; MOSI2;
D O I
10.1016/j.ceramint.2023.08.351
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
To suppress the oxidation loosening of HfB2-SiC coating, the HfB2 was alloyed with HfSi2 in the form of composite powders through self-propagating high-temperature synthesis (SHS) technique, which was then used to prepare HfB2-HfSi2-SiC coatings. Compared to the 60HfB2-SiC coating, the 60(HfB2-HfSi2)SHS-SiC coating exhibited lower oxidation activity and better inert oxygen blocking at 1700 degrees C. The addition of HfSi2 promoted the homogenization of the Hf-oxides distribution on the glass layer and the formation of the protective phase HfSiO4, further inhibiting oxygen diffusion. The 60(80HfB2-20HfSi2)SHS-SiC coating exhibited optimal oxygen blocking protection after oxidation at 1700 degrees C, with 87.96% and 92.33% reductions in oxygen permeability and carbon loss rate, respectively.
引用
收藏
页码:36679 / 36690
页数:12
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