Asymmetric Synthesis of Contact Pheromone Component of Xylotrechus colonus and Its Analogues

被引：0

作者：

Yuan, Chaonan ^{[1
]}

Wu, Jianwei ^{[1
]}

Yu, Shihang ^{[1
]}

Bian, Qinghua ^{[1
]}

Wang, Min ^{[1
]}

Liu, Dan ^{[1
]}

Zhong, Jiangchun ^{[1
]}

机构：

[1] China Agr Univ, Dept Appl Chem, 2 West Yuanmingyuan Rd, Beijing 100193, Peoples R China

来源：

CHEMISTRYSELECT | 2023年 / 8卷 / 13期

关键词：

asymmetric synthesis; catalytic hydrogenation; chiral phosphonium salt; contact pheromone; Xylotrechus colonus; SEX-PHEROMONE; METATHESIS; RING;

D O I：

10.1002/slct.202204807

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Xylotrechus colonus is an abundant wood-boring pest of woody plants. 3-Methylpentacosane was identified as the component of its contact pheromone. A novel and efficient asymmetric synthesis of (S)-3-methylpentacosane and its analogues was developed using (S)-2-methylbutan-1-ol as chiral source. The key of this approach included Wittig coupling of chiral phosphonium salt with aldehyde, Pd-catalyzed hydrogenation and Appel reaction. Our synthesis would be helpful for the control and detect of this pest.

引用

页数：5

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