New Insights into the Structure, Properties, and Applications of Polyhedral Oligomeric Silsesquioxane

被引:9
|
作者
Moein, Abolfazl [1 ]
Kebritchi, Abbas [1 ]
机构
[1] Imam Hossein Comprehens Univ, Chem Engn Dept, Tehran, Iran
关键词
POSS; Nanostructure; Rheological properties; Mechanical properties; Thermal properties; HYBRID AQUEOUS DISPERSIONS; GAS-TRANSPORT PROPERTIES; MECHANICAL-PROPERTIES; FLAME RETARDANCY; VISCOELASTIC BEHAVIOR; POSS NANOCOMPOSITES; THERMAL-PROPERTIES; EPOXY-RESIN; COMPOSITES; MORPHOLOGY;
D O I
10.1007/s12633-023-02494-4
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
One of the approaches to improve the properties of polymers is to use additives in them. In the last few years, nanoscale additives have received attention due to the favorable properties they give to polymers in low concentrations. POSS or polyhedral oligomeric silsesquioxane has unique properties due to its nanometer size and organic-inorganic nature. The rigid structure of POSS and its compatibility with all types of polymers make their use attractive in various polymer industries. The concentration, structure of the mineral core, and type of POSS organic groups can affect the final properties of polymers containing these nanostructures. Chemical mixing of POSS with polymer increases the viscosity of the system, while physical mixing decreases the viscosity of the polymer. These nanostructures can improve properties such as tensile strength, modulus, and toughness of the polymer. Polymers with low concentrations of POSS have the advantage of high thermal stability and low flammability, which makes them ideal for applications in the aerospace industry where materials must withstand extreme temperatures and harsh environments. In addition, the low dielectric constant of POSS-containing polymers makes them useful for use in electronic components. The high specific surface of POSS allows the use of these nanostructures as supports for various catalysts. POSS is used in a wide range of industries including aerospace, biomedical, electronics and chromatography columns, etc.
引用
收藏
页码:5845 / 5875
页数:31
相关论文
共 50 条
  • [31] Polyimide and polyhedral oligomeric silsesquioxane nanocomposites for low-dielectric applications
    Lee, YJ
    Huang, JM
    Kuo, SW
    Lu, JS
    Chang, FC
    POLYMER, 2005, 46 (01) : 173 - 181
  • [32] Synthesis, Structure, and Properties of High-Impact Polystyrene/Octavinyl Polyhedral Oligomeric Silsesquioxane Nanocomposites
    Hu, Kun
    Cui, Zhong-Kai
    Yuan, Yongliang
    Zhuang, Qixin
    Wang, Tongxin
    Liu, Xiaoyun
    Han, Zhewen
    POLYMER COMPOSITES, 2016, 37 (04) : 1049 - 1055
  • [33] Structure of copper(II) complexes adsorbed on functionalized polyhedral oligomeric silsesquioxane
    Dias Filho, Newton Luiz
    Costa, Reginaldo Mendonca
    Schultz, Mario Sergio
    INORGANICA CHIMICA ACTA, 2008, 361 (08) : 2314 - 2320
  • [34] Effect of Polyhedral Oligomeric Silsesquioxane on the Melting, Structure, and Mechanical Behavior of Polyoxymethylene
    Czarnecka-Komorowska, Dorota
    Sterzynski, Tomasz
    POLYMERS, 2018, 10 (02)
  • [35] Thermal and bulk properties of montmorillonite modified with aminoethylaminopropylisobutyl polyhedral oligomeric silsesquioxane
    Lewis, Elana C.
    Morgan, Sarah E.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2011, 242
  • [36] Synthesis and properties of polyhedral oligomeric silsesquioxane (POSS) fluorinated acrylate polymers
    Guan, Xinghua
    Qiang, Xiu
    Ma, Xiaoyan
    Xia, Yu
    Yu, Tao
    Hou, Xianbing
    Xibei Gongye Daxue Xuebao/Journal of Northwestern Polytechnical University, 2015, 33 (04): : 699 - 705
  • [37] Synthesis and properties of aromatic polyamide dendrimers with polyhedral oligomeric silsesquioxane cores
    Matsumoto, Kazuya
    Nishi, Kunio
    Ando, Kimiko
    Jikei, Mitsutoshi
    POLYMER CHEMISTRY, 2015, 6 (26) : 4758 - 4765
  • [38] Thermal and mechanical properties of polymethyl mathacrylate reinforced by polyhedral oligomeric silsesquioxane
    Yang, Benghong
    Li, Meng
    Song, Bangping
    Wu, Yun
    E-POLYMERS, 2011,
  • [39] A Study on Physical Properties of EPDM/Polyhedral Oligomeric Silsesquioxane (POSS) Composites
    Park, Hyun-Ho
    APPLIED CHEMISTRY FOR ENGINEERING, 2021, 32 (04): : 472 - 477
  • [40] Mechanical properties of dental nanocomposites reinforced with polyhedral oligomeric silsesquioxane(POSS)
    Wu, Xiaorong
    Xie, Weili
    Sun, Yi
    Sun, Shouhua
    MULTI-FUNCTIONAL MATERIALS AND STRUCTURES II, PTS 1 AND 2, 2009, 79-82 : 345 - +