Low-Temperature Chemical Bath Deposition of Conformal and Compact NiOX for Scalable and Efficient Perovskite Solar Modules

被引:10
|
作者
Li, Sibo [1 ,2 ]
Wang, Xin [2 ]
Li, Huan [2 ]
Fang, Jun [2 ]
Wang, Daozeng [2 ]
Xie, Guanshui [2 ]
Lin, Dongxu [2 ]
He, Sisi [1 ,3 ]
Qiu, Longbin [2 ]
机构
[1] Harbin Inst Technol, Sch Chem & Chem Engn, Harbin 150001, Peoples R China
[2] Southern Univ Sci & Technol, SUSTech Energy Inst Carbon Neutral, Dept Mech & Energy Engn, Shenzhen 518055, Peoples R China
[3] Harbin Inst Technol Shenzhen, Flexible Printed Elect Technol Ctr, Sch Sci, Shenzhen 518055, Peoples R China
基金
中国国家自然科学基金;
关键词
chemical bath deposition; low temperatures; nickel oxide; perovskite solar cells; modules; scalability; HOLE-TRANSPORT LAYERS; SOLUTION-PROCESSED PEROVSKITE; NICKEL-OXIDE; CELLS; METAL; XPS;
D O I
10.1002/smll.202301110
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A scalable and low-cost deposition of high-quality charge transport layers and photoactive perovskite layers are the grand challenges for large-area and efficient perovskite solar modules and tandem cells. An inverted structure with an inorganic hole transport layer is expected for long-term stability. Among various hole transport materials, nickel oxide has been investigated for highly efficient and stable perovskite solar cells. However, the reported deposition methods are either difficult for large-scale conformal deposition or require a high vacuum process. Chemical bath deposition is supposed to realize a uniform, conformal, and scalable coating by a solution process. However, the conventional chemical bath deposition requires a high annealing temperature of over 400 degrees C. In this work, an amino-alcohol ligand-based controllable release and deposition of NiOX using chemical bath deposition with a low calcining temperature of 270 degrees C is developed. The uniform and conformal in-situ growth precursive films can be adjusted by tuning the ligand structure. The inverted structured perovskite solar cells and large-area solar modules reached a champion PCE of 22.03% and 19.03%, respectively. This study paves an efficient, low-temperature, and scalable chemical bath deposition route for large-area NiOX thin films for the scalable fabrication of highly efficient perovskite solar modules.
引用
收藏
页数:9
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