Treatment of landfill leachate by combined use of ultrasound and photocatalytic process using fly ash as catalyst

Advanced oxidation processes, such as sonophotocatalysis and photocatalysis, have been proven to be interesting alternatives for the effective treatment of old landfill leachates. Since there is no specific information about which parameters help to improve the treatment efficiency when using fly ash (FA) in a sonophotoreactor, this research focuses on evaluating the use of an ultrasound process (US) combined with a photo-Fenton process, with FA as a catalyst for the first time. The removals of colour, chemical oxygen demand (COD), and aromatic compounds (UV 254) present in landfill leachates were studied using a factorial design, where the effect of different loads of FA (1, 1.5, and 2 g FA/L), pH (pH = 3, 6, and 8.9), and US frequency irradiation (576, 864, and 1138 kHz) on the efficiency of photo-Fenton was evaluated. The highest removals of COD (40.7%), colour (36.8%), and UV 254 (50.8%) were achieved adjusting the pH to 3, adding 2 g of FA/L, and applying 576 kHz of US frequency. It was found that pH is the parameter that has the highest effect on pollutant removal (95% confidence level). In addition, the removals of COD, colour, and UV 254 increased at lower pH values and US frequency. Also, the presence of Fe2O3, SiO2, and TiO2 in the FA under UV irradiation and ultrasound process, improved the removal of complex organic matter present in the landfill leachate, where HO center dot was the most important radical.