Push-pull [7]helicene diimide: excited-state charge transfer and solvatochromic circularly polarised luminescence

被引：5

作者：

Saal, Fridolin ^{[1
]}

Swain, Asim ^{[1
]}

Schmiedel, Alexander ^{[1
]}

Holzapfel, Marco ^{[1
]}

Lambert, Christoph ^{[1
]}

Ravat, Prince ^{[1
]}

机构：

[1] Julius Maximilians Univ Wurzburg, Inst Organ Chem, D-97074 Wurzburg, Germany

来源：

CHEMICAL COMMUNICATIONS | 2023年 / 59卷 / 94期

基金：

欧洲研究理事会;

关键词：

All Open Access; Green;

D O I：

10.1039/d3cc04470j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this communication we describe a helically chiral push-pull molecule named 9,10-dimethoxy-[7]helicene diimide, displaying fluorescence (FL) and circularly polarised luminescence (CPL) over nearly the entire visible spectrum dependent on solvent polarity. The synthesised molecule exhibits an unusual solvent polarity dependence of FL quantum yield and nonradiative rate constant, as well as remarkable gabs and glum values along with high configurational stability. Herein we describe a helically chiral push-pull molecule named 9,10-dimethoxy-[7]helicene diimide, displaying fluorescence and CPL over nearly the entire visible spectrum dependent on solvent polarity along with high dissymmetry factors.

引用

页码：14005 / 14008

页数：4

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