Bimetallic Coordination Polymers Based on Acenaphthene-1,2-diimine Ligand

被引：0
|
作者：
Koptseva, T. S. [1 ]
Bazyakina, N. L. [1 ]
Kozlova, E. A. [1 ]
Fedushkin, I. L. [1 ]
机构：
[1] Russian Acad Sci, GA Razuvaev Inst Organometall Chem, Nizhnii Novgorod 603137, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2023年 / 93卷 / SUPPL 3期
基金：
俄罗斯科学基金会;
关键词：
metal-organic coordination polymers; aluminum; gallium; sodium; acenaphthene-1,2-diimines; METAL-ORGANIC FRAMEWORKS; COMPLEXES; MOFS;
D O I：
10.1134/S107036322316020X
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
One-dimensional metalorganic coordination polymers [{(dpp-bian(2-))M(mu(2)-S)(2)M(dpp-bian(2-))Na-2(THF)(4)}center dot (mu-4,4 '-bipy)center dot 2THF](n) {M = Al, Ga; dpp-bian = 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene, 4,4 '-bipy = 4,4 '-bipyridine} were obtained by a series of successive reactions of dimetalanes [(dpp-bian2-)M-M(dpp-bian2-)] (M = Al, Ga) with sulfur, sodium and 4,4 '-bipyridine. The prepared compounds were characterized by elemental analysis, IR spectroscopy, and single crystal X-ray diffraction analysis. The thermal stability of the compounds was studied by thermogravimetric analysis (TGA).
引用
收藏
页码：S814 / S821
页数：8
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