Ligand-directed structure evolution from a titanium-oxo cluster to coordination capsule and one-dimensional coordination polymer based on {Ti3O} units

被引:2
|
作者
Meng, Min [1 ]
Liao, Lingrong [2 ]
Zheng, Qi [2 ]
Xuan, Weimin [1 ]
机构
[1] Donghua Univ, State Key Lab Modificat Chem Fibers & Polymer Mat, Shanghai 201620, Peoples R China
[2] Donghua Univ, Coll Mat Sci & Engn, Shanghai 201620, Peoples R China
基金
中国国家自然科学基金;
关键词
METAL-ORGANIC FRAMEWORK; PHOTOELECTROCHEMICAL PROPERTIES; DESIGN; CARBOXYLATE; TRINUCLEAR; CO2; NANOCLUSTER; FAMILY; SERIES; SITES;
D O I
10.1039/d3nj01172k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
By modulating the geometry and size of the ligand and using phosphite as a bridging linker, {Ti-3(mu(3)-O)} can be assembled into a discrete {Ti-6} cluster, coordination capsule {Ti18Cu3} and one-dimensional coordination polymer {Ti-6}(n).
引用
收藏
页码:11312 / 11317
页数:6
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