Julia-Kocienski Olefination: A Tutorial Review

被引：14

作者：

Sakaine, Guna ^{[1
]}

Leitis, Zigmars ^{[1
]}

Locmele, Rebeka ^{[1
]}

Smits, Gints ^{[1
]}

机构：

[1] Latvian Inst Organ Synth, Lab CNS Act Cpds, Aizkraukles 21, Riga, Latvia

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2023年 / 26卷 / 07期

关键词：

Julia-Kocienski olefination; natural products; total synthesis; synthetic methods; stereoselectivity; ENANTIOSELECTIVE TOTAL-SYNTHESIS; CARBONYL-COMPOUNDS; SULFONES; DERIVATIVES; STEREOCHEMISTRY; ASSIGNMENT;

D O I：

10.1002/ejoc.202201217

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Over the past two decades, Julia-Kocienski olefination has become one of the most powerful and reliable C=C double-bond construction methods typically furnishing E-configured alkenes. This review summarizes the scientific literature of the past decade focusing on the key aspects for successful execution of the olefination step. The main stereoselectivity and yield-determining aspects have been outlined in separate chapters providing all the necessary information for the synthesis of Julia-Kocienski reagents as well as the most commonly used reaction optimization techniques.

引用

页数：9

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