Julia-Kocienski Olefination: A Tutorial Review

被引：14
|
作者：
Sakaine, Guna [1 ]
Leitis, Zigmars [1 ]
Locmele, Rebeka [1 ]
Smits, Gints [1 ]
机构：
[1] Latvian Inst Organ Synth, Lab CNS Act Cpds, Aizkraukles 21, Riga, Latvia
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2023年 / 26卷 / 07期
关键词：
Julia-Kocienski olefination; natural products; total synthesis; synthetic methods; stereoselectivity; ENANTIOSELECTIVE TOTAL-SYNTHESIS; CARBONYL-COMPOUNDS; SULFONES; DERIVATIVES; STEREOCHEMISTRY; ASSIGNMENT;
D O I：
10.1002/ejoc.202201217
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Over the past two decades, Julia-Kocienski olefination has become one of the most powerful and reliable C=C double-bond construction methods typically furnishing E-configured alkenes. This review summarizes the scientific literature of the past decade focusing on the key aspects for successful execution of the olefination step. The main stereoselectivity and yield-determining aspects have been outlined in separate chapters providing all the necessary information for the synthesis of Julia-Kocienski reagents as well as the most commonly used reaction optimization techniques.
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页数：9
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