An air-stable radical with a redox-chameleonic amide

被引：7

作者：

Peltier, Jesse L. ^{[1
]}

Serrato, Melinda R. ^{[1
]}

Thery, Valentin ^{[2
]}

Pecaut, Jacques ^{[3
]}

Tomas-Mendivil, Eder ^{[2
]}

Bertrand, Guy ^{[1
]}

Jazzar, Rodolphe ^{[1
]}

Martin, David ^{[2
]}

机构：

[1] Univ Calif San Diego, Dept Chem & Biochem, UCSD CNRS Joint Res Chem Lab IRL 3555, La Jolla, CA 92093 USA

[2] Univ Grenoble Alpes, DCM, CNRS, F-38000 Grenoble, France

[3] Univ Grenoble Alpes, INAC SyMMES, CNRS, CEA,UMR 5819, F-38000 Grenoble, France

来源：

CHEMICAL COMMUNICATIONS | 2023年 / 59卷 / 05期

关键词：

SELECTIVE PHOTOCYCLIZATION; AMINO-ACIDS; CARBENES; STABILITY; 2-QUINUCLIDONIUM; REACTIVITY; COMPLEXES; OXIDATION; METALS; CATION;

D O I：

10.1039/d2cc05404c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An air-stable (amino)(amido)radical was synthesized by reacting a cyclic (alkyl)(amino)carbene with carbazoyl chloride, followed by one-electron reduction. We show that an adjacent radical center weakens the amide bond. It enables the amino group to act as a strong acceptor under steric contraint, thus enhancing the stabilizing capto-dative effect.

引用

页码：595 / 598

页数：4

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