Viscosity of anhydrous and hydrous peridotite melts

被引:7
|
作者
Di Genova, Danilo [1 ,2 ]
Bondar, Dmitry [1 ]
Zandona, Alessio [3 ,4 ]
Valdivia, Pedro [1 ]
Al-Mukadam, Raschid [5 ]
Fei, Hongzhan [1 ]
Withers, Anthony C. [1 ]
Ballaran, Tiziana Boffa [1 ]
Kurnosov, Alexander [2 ]
McCammon, Catherine [1 ]
Deubener, Joachim [5 ]
Katsura, Tomoo [1 ]
机构
[1] Univ Bayreuth, Bayer Geoinst, Univ Str 30, D-95440 Bayreuth, Germany
[2] Natl Res Council Italy, Inst Environm Geol & Geoengn, Rome, Italy
[3] Univ Orleans, CNRS, CEMHTI UPR3079, F-45071 Orleans, France
[4] Friedrich Alexander Univ Erlangen Nurnberg, Dept Mat Sci Glass & Ceram, Martensstr 5, D-91058 Erlangen, Germany
[5] Tech Univ Clausthal, Inst Nonmetall Mat, Zehntnerstr 2a, D-38678 Clausthal Zellerfeld, Germany
基金
欧洲研究理事会;
关键词
Peridotite melt; Viscosity; Glass transition; Calorimetry; Brillouin spectroscopy; GLASS-TRANSITION TEMPERATURE; SILICATE-GLASSES; FICTIVE TEMPERATURE; OXIDATION-STATE; OXYGEN FUGACITY; HIGH-PRESSURE; MAGMA OCEAN; WATER; MANTLE; LIQUIDS;
D O I
10.1016/j.chemgeo.2023.121440
中图分类号
P3 [地球物理学]; P59 [地球化学];
学科分类号
0708 ; 070902 ;
摘要
The melt viscosity (eta) of anhydrous and hydrous peridotite was investigated using a multipronged approach combining micropenetration viscometry, conventional DSC, flash DSC and Brillouin spectroscopy. Raman spectroscopy measurements were used to verify the absence of crystallization and/or degassing during hightemperature measurements of these extremely reactive glasses and melts, ensuring that the data corresponded to the crystal-free melt viscosity. Based on the experimental data, an accurate description of the viscosity of peridotite melts over thirteen orders of magnitude (from Tg to eta approximate to 10-1 Pa s) is provided in a broad range of compositions and oxidation states. Since empirical models predict viscosities that can significantly deviate from measured data to varying degrees, a new model was developed for the temperature- and H2O-dependent viscosity of peridotite melts (up to 12 mol% H2O content).
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页数:13
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