Molecular rotation induced giant, anisotropic negative thermal expansion in a hydrogen-bonded coordination framework

被引：7

作者：

Meng, Peng ^{[1
]}

Brock, Aidan ^{[1
]}

Wang, Xiaodong ^{[2
]}

Wang, Yuting ^{[1
]}

McMurtrie, John ^{[1
]}

Xu, Jingsan ^{[1
]}

机构：

[1] Queensland Univ Technol, Ctr Mat Sci, Sch Chem & Phys, Brisbane, Qld 4000, Australia

[2] Queensland Univ Technol, Inst Future Environm, Cent Analyt Res Facil, Brisbane, Qld 4000, Australia

来源：

INORGANIC CHEMISTRY FRONTIERS | 2023年 / 10卷 / 08期

关键词：

D O I：

10.1039/d2qi02265f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Negative thermal expansion (NTE) is generally caused by the transverse vibration of the bridging groups. Herein, we report a new supramolecular structure of cyanuric acid-melamine-zinc (CA-M-Zn) demonstrating unique molecular rotation induced NTE along the c axis (volumetric expansion coefficient alpha(v) = -197 x 10(-6) K-1, linear expansion coefficient alpha(c) = -242 x 10(-6) K-1), accompanied by a significant decrease of beta angle (-3.8%).

引用

页码：2399 / 2403

页数：5

共 50 条

[31] Hydrogen-Bonded Organic Framework Microlasers with Conformation-Induced Color-Tunable Output
Lv, Yuanchao
Li, Delin
Ren, Ang
Xiong, Zhile
Yao, Yinan
Cai, Kaicong
Xiang, Shengchang
Zhang, Zhangjing
Zhao, Yong Sheng
ACS APPLIED MATERIALS & INTERFACES, 2021, 13 (24) : 28662 - 28667
[32] Pressure-induced hydrogen localization coupled to a semiconductor-insulator transition in a hydrogen-bonded molecular conductor
Ueda, Akira
Kishimoto, Kouki
Isono, Takayuki
Yamada, Shota
Kamo, Hiromichi
Kobayashi, Kensuke
Kumai, Reiji
Murakami, Youichi
Gouchi, Jun
Uwatoko, Yoshiya
Nishio, Yutaka
Mori, Hatsumi
RSC ADVANCES, 2019, 9 (32): : 18353 - 18358
[33] Giant Zn14 Molecular Building Block in Hydrogen-Bonded Network with Permanent Porosity for Gas Uptake
Mondal, Suvendu Sekhar
Bhunia, Asamanjoy
Kelling, Alexandra
Schilde, Uwe
Janiak, Christoph
Holdt, Hans-Juergen
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (01) : 44 - 47
[34] Framework-Shrinkage-Induced Wavelength-Switchable Lasing from a Single Hydrogen-Bonded Organic Framework Microcrystal
Lv, Yuanchao
Xiong, Zhile
Li, Yunbin
Li, Delin
Liang, Jiashuai
Yang, Yisi
Xiang, Fahui
Xiang, Shengchang
Zhao, Yong Sheng
Zhang, Zhangjing
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2022, 13 (01): : 130 - 135
[35] Enhanced negative thermal expansion in MFI molecular sieves by varying framework composition
Bhange, D. S.
Ramaswamy, Veda
MICROPOROUS AND MESOPOROUS MATERIALS, 2010, 130 (1-3) : 322 - 326
[36] High-Efficiency Lithium-Ion Transport in a Porous Coordination Chain-Based Hydrogen-Bonded Framework
Han, Zongsu
Zhang, Runhao
Jiang, Jialong
Chen, Zhonghang
Ni, Youxuan
Xie, Weiwei
Xu, Jun
Zhou, Zhen
Chen, Jun
Cheng, Peng
Shi, Wei
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2023, 145 (18) : 10149 - 10158
[37] Giant negative linear compression positively coupled to massive thermal expansion in a metal–organic framework
Weizhao Cai
Andrzej Katrusiak
Nature Communications, 5
[38] Hydrogen-Bonded Organic Framework Nanoscintillators for X-Ray-Induced Photodynamic Therapy in Hepatocellular Carcinoma
Gu, Lihui
Wu, Han
Li, Xu
Xu, Jiahao
Wang, Mingda
Li, Chao
Yao, Lanqing
Diao, Yongkang
Li, Yuchen
Chen, Fujie
Shen, Feng
Xiang, Huijing
Chen, Yu
Yang, Tian
ADVANCED MATERIALS, 2025,
[39] Deuteration-Enhanced Negative Thermal Expansion and Negative Area Compressibility in a Three-Dimensional Hydrogen Bonded Network
Rejnhardt, Piotr
Zareba, Jan K.
Katrusiak, Andrzej
Daszkiewicz, Marek
CHEMISTRY OF MATERIALS, 2023, 35 (13) : 5160 - 5167
[40] Anisotropic Superprotonic Conduction in a Layered Single-Component Hydrogen-Bonded Organic Framework with Multiple In-Plane Open Channels
Wang, Zhiwei
Yang, Lijuan
Chen, Qian
Liu, Peiyuan
Yang, Zhiwei
Li, Hai
Huang, Xiao
Huang, Wei
ADVANCED MATERIALS, 2024, 36 (40)

← 1 2 3 4 5 →