An egg-shell PdAg/a-Al2O3 single-atom alloy catalyst for selective acetylene hydrogenation

被引：7
|
作者：
Markov, Pavel, V [1 ]
Mashkovsky, Igor S. [1 ]
Baeva, Galina N. [1 ]
Melnikov, Dmitry P. [1 ]
Stakheev, Alexander Yu. [1 ]
机构：
[1] Russian Acad Sci, N D Zelinsky Inst Organ Chem, Moscow 119991, Russia
来源：
MENDELEEV COMMUNICATIONS | 2023年 / 33卷 / 06期
基金：
俄罗斯科学基金会;
关键词：
acetylene hydrogenation; egg-shell catalyst; single-atom alloy catalyst; PdAg alloy; heterobimetallic complex; catalyst characterization; ETHENE-RICH STREAMS; PD-AG/AL2O3; CATALYSTS; PALLADIUM CATALYSTS; PD NANOPARTICLES; PARTICLE-SIZE; DEACTIVATION; PERFORMANCE; ETHYNE; XPS;
D O I：
10.1016/j.mencom.2023.10.032
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The PdAg/a-Al2O3 catalyst with an egg-shell distribution of single-atom alloy (SAA) Pd1Ag nanoparticles was obtained using the complex PdAg2(OAc)4(HOAc)4 as a precursor and characterized by FESEM-EDS, XPS, and DRIFTS CO analysis. The egg-shell Pd1Ag SAA catalyst demonstrated superior selectivity in the hydrogenation of acetylene in acetylene-ethylene feed.
引用
收藏
页码：836 / 838
页数：3
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