Visible-Light-Promoted Trifluoromethylthiolation and Trifluoromethylselenolation of 1,4-Dihydropyridines

被引：13
|
作者：
Shan, Xiwen [1 ]
Wang, Xiaoxing [1 ]
Chen, Enxue [1 ]
Liu, Juyan [1 ]
Lu, Kui [1 ]
Zhao, Xia [1 ]
机构：
[1] Tianjin Normal Univ, Coll Chem, Tianjin Key Lab Struct & Performance Funct Mol, Tianjin 300387, Peoples R China
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2023年 / 88卷 / 01期
基金：
中国国家自然科学基金;
关键词：
ELECTRON-RICH AROMATICS; TRIFLUOROMETHANESULFONYL CHLORIDE; ALKENES; INDOLES; ESTERS; DIFLUOROMETHYLTHIOLATION; REAGENTS; CF3SO2NA;
D O I：
10.1021/acs.joc.2c02348
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
We report a metal-free trifluoromethylthiolation and trifluoromethylselenolation of 1,4-dihydropyridines with S-(tri-fluoromethyl) 4-methylbenzenesulfonothioate and Se-(trifluoro-methyl) 4-methylbenzenesulfonoselenoate under visible light irradiation. This transformation was tolerated with a wide range of functional groups and provided an alternative and green strategy for the synthesis of trifluoromethylthioesters and trifluoromethyl-selenoesters.
引用
收藏
页码：319 / 328
页数：10
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