Thio(seleno)cyano-difluoroalkylation of Alkenes Using Visible-Light Photocatalysis

被引：17
|
作者：
Choi, Ye Rin [1 ]
Lee, Seok Beom [2 ]
Lee, Jae Kyun [3 ]
Kwak, Yoonna [1 ]
An, Hongchan [1 ]
Choi, Sungwook [2 ]
Hong, Ki Bum [1 ]
机构：
[1] Daegu Gyeongbuk Med Innovat Fdn DGMIF, New Drug Dev Ctr NDDC, Daegu 41061, South Korea
[2] Chungnam Natl Univ, Dept New Drug Discovery & Dev, Daejeon 34134, South Korea
[3] Brain Sci Inst, Korea Inst Sci & Technol KIST, Seoul 02792, South Korea
来源：
ORGANIC LETTERS | 2023年 / 25卷 / 19期
基金：
新加坡国家研究基金会;
关键词：
D O I：
10.1021/acs.orglett.3c01206
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A mild and efficient three-component thio(seleno)cyano-difluoroalkylation of simple alkenes is demonstrated using an iridium(ruthenium) photocatalyst. This protocol provides a direct and regioselective installation of both C-S(Se)CN [thio(seleno)cyanation] and C-CF (difluoroalkylation) bonds.
引用
收藏
页码：3564 / 3567
页数：4
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