Palladium-catalyzed allylic allenylation of homoallyl alcohols with propargylic carbonates

被引：7

作者：

Zhou, Ping-Xin ^{[1
]}

Wang, Murong ^{[1
]}

Li, Xiang ^{[1
]}

Du, Xueyan ^{[1
]}

Yang, Xiaozhe ^{[1
]}

Wang, Han ^{[1
]}

Sun, Tangqiang ^{[3
]}

Ren, Feng ^{[1
,2
]}

Liang, Yong-Min ^{[4
]}

机构：

[1] Xinxiang Med Univ, Sch Basic Med Sci, Xinxiang, Peoples R China

[2] Xinxiang Med Univ, Henan Int Joint Lab Immun & Targeted Therapy liver, Xinxiang, Peoples R China

[3] Xinxiang Med Univ, Coll Pharm, Xinxiang, Peoples R China

[4] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou, Peoples R China

来源：

ORGANIC CHEMISTRY FRONTIERS | 2023年 / 10卷 / 08期

关键词：

TOSYLHYDRAZONE INSERTION REACTION; HIGHLY EFFICIENT SYNTHESIS; ARYL HALIDES; COUPLING REACTION; ALLENES; ALLYLATION; REAGENTS; ALLENYLPHOSPHONATES; ACETATES; BEARING;

D O I：

10.1039/d3qo00025g

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A palladium-catalyzed reaction of homoallyl alcohols with propargylic carbonates was realized via oxidative addition/decarboxylation/retro-allylation. The reaction proceeds with a wide substrate scope by using readily available starting materials, which provides a new and efficient method to synthesize a series of tri- and tetra-substituted allyl allenes.

引用

页码：2033 / 2038

页数：6

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