Synthesis of Carboxylic Acids from Saccharides, CO2, and H2

被引：4

作者：

Li, Yang ^{[1
,2
]}

Wang, Ying ^{[1
]}

Zhang, Yanru ^{[1
,2
]}

Wang, Zhenpeng ^{[1
]}

Xiang, Junfeng ^{[1
]}

Han, Juanjuan ^{[1
]}

He, Jun ^{[1
]}

Zhang, Longbo ^{[1
,2
]}

Wang, Yanyan ^{[1
,2
]}

Meng, Qinglei ^{[1
]}

Qian, Qingli ^{[1
,3
]}

Han, Buxing ^{[1
,2
,3
,4
]}

机构：

[1] Chinese Acad Sci, Inst Chem, CAS Res Educ Ctr Excellence Mol Sci, CAS Key Lab Colloid Interface & Chem Thermodynam,B, Beijing 100190, Peoples R China

[2] Univ Chinese Acad Sci, Sch Chem & Chem Engn, Beijing 100049, Peoples R China

[3] Huairou Natl Comprehens Sci Ctr, Phys Sci Lab, Beijing 101400, Peoples R China

[4] East China Normal Univ, Sch Chem & Mol Engn, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China

来源：

ACS CATALYSIS | 2023年 / 13卷 / 12期

基金：

中国国家自然科学基金;

关键词：

carbon dioxide; biomass; saccharides; carboxylic acids; homogeneous catalysis; CARBON-DIOXIDE; CONVERSION; BIOMASS; ISOMERIZATION; CHEMICALS; GLUCOSE;

D O I：

10.1021/acscatal.3c00374

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Here we report a strategy to synthesize C-7 carboxylicacids via the reaction of glucose, CO2 and H-2. The reaction can be realized using Rh-(acac)-(CO)(2) ascatalyst and I-2 as promoter in the binary solvent of aceticacid and water at 160 degrees C. The strategy also applies to otherC(n) saccharides, where the corresponding Cn+1 carboxylic acids could be obtained and the yield of the acids canreach 72% when glyceraldehyde was used. The reaction pathway was proposedbased on a series of control experiments. This work utilized saccharideand CO2 simultaneously via C-C bond formation, whichopens a promising way of biomass utilization and CO2 conversion.

引用

页码：8025 / 8030

页数：6

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