[4,4'-Bis(4-fluorophenyl)-6,6'-dimethyl-2,2'-bipyridine] [bis (2-(diphenylphosphino) phenyl) ether] Silver(I) Hexafluorophosphate

被引：2
|
作者：
Glykos, Dimitrios [1 ]
Plakatouras, John C. [1 ,2 ]
Malandrinos, Gerasimos [1 ]
机构：
[1] Univ Ioannina, Dept Chem, Lab Inorgan Chem, Ioannina 45110, Greece
[2] Univ Res Ctr Ioannina, Inst Mat Sci & Comp, Ioannina 45110, Greece
来源：
MOLBANK | 2023年 / 2023卷 / 03期
关键词：
silver(I) complex; luminescence; diimine ligands; X-ray diffraction; LUMINESCENT PROPERTIES; DIPHOSPHINE LIGANDS; AG(I) COMPLEXES; CELLS;
D O I：
10.3390/M1675
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A new emissive heteroleptic Ag(I) complex formulated as [AgL(POP)][PF6] (L = 4,4 & PRIME;-bis (4-Fluorophenyl)-6,6 & PRIME;-dimethyl-2,2 & PRIME;-bipyridine, POP= bis (2-(diphenylphosphino) phenyl) ether) was synthesized and characterized in both the solid state (X-ray crystallography) and the solution. The compound is a yellow-green phosphor (& lambda;em = 528 nm), with moderate quantum efficiency (& phi;PL = 25% in deaerated dichloromethane).
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页数：8
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