Oxygen bubble transport in a porous transport layer of polymer electrolyte water electrolyzer

被引:20
|
作者
Jeon, Dong Hyup [1 ,2 ]
Kim, Sangwon [2 ]
Kim, MinJoong [3 ]
Lee, Changsoo [3 ]
Cho, Hyun-Seok [3 ]
机构
[1] Dongguk Univ, Dept Mech Syst Engn, Gyeongju 38066, South Korea
[2] Korea Inst Sci & Technol Europe, D-66123 Saarbrucken, Germany
[3] Korea Inst Energy Res, Hydrogen Res Dept, Daejeon 34129, South Korea
基金
新加坡国家研究基金会;
关键词
Porous transport layer; Proton exchange water electrolyzer; Lattice Boltzmann simulation; Oxygen bubble; Buoyancy-driven transport; LATTICE BOLTZMANN METHOD; NEUTRON-RADIOGRAPHY; 2-PHASE FLOW; MODEL; PERFORMANCE; SITU;
D O I
10.1016/j.jpowsour.2022.232322
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Considerable efforts have been taken to develop an effective porous transport layer (PTL) that can mitigate the mass transport resistance of proton exchange water electrolysis (PEWE). Several experiments have been con-ducted to understand the underlying mechanisms in the PTL that are responsible for bubble removal and per-formance improvement. Here, we investigate the dynamic behavior of oxygen bubble in a PTL using a free surface model in a lattice Boltzmann framework. Various PTL properties are examined to gain a fundamental understanding of the bubble transport phenomena and perform effective bubble removal from the PTL at a high current density operation. We report on the bubble volume fraction and bubble distribution inside the PTL to elucidate the impact of the PTL properties on the bubble transport behavior. Oxygen bubble transport charac-teristics that determine the bubble removal time have been extensively studied. The findings will enable more reliable bubble management and the development of related high-power PEWE technologies.
引用
收藏
页数:10
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