Nucleophilic Addition of Aliphatic Diamines NH2(CH2)nNH2 (n=6, 9) to Nitrilium Derivatives of the closo-Decaborate Anion [2-B10H9NCR]- (R = CH3, C2H5, nC3H7)

被引：0

作者：

Voinova, V. V. ^{[1
]}

Selivanov, N. A. ^{[1
]}

Bykov, A. Yu. ^{[1
]}

Klyukin, I. N. ^{[1
]}

Zhdanov, A. P. ^{[1
]}

Zhizhin, K. Yu. ^{[1
]}

Kuznetsov, N. T. ^{[1
]}

机构：

[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2023年 / 68卷 / 10期

关键词：

closo-decaborate anion; amidines; polyfunctional nucleophiles; CARBOXYLIC-ACIDS; METHANE; DODECABORATE; ESTERS; ROUTE;

D O I：

10.1134/S0036023623601885

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of a number of nitrilium derivatives of the closo-decaborate anion with hexamethylene- and nonamethylenediamine has been studied. It has been shown that the process proceeds with the functionalization of both amino groups of the nucleophile to form amidines of the type (Bu4N)(2)[B10H9NH=C(R)NH (CH2)(n)NH(R)C=NHB10H9] (R = CH3, C2H5, (C3H7)-C-n; n = 6, 9). Target compounds have been characterized by high resolution multinuclear NMR and ESI mass spectrometry.

引用

页码：1343 / 1348

页数：6

共 50 条

[41] Unimolecular reactivity of organotrifluoroborate anions, RBF3-, and their alkali metal cluster ions, M(RBF3)2- (M = Na, K; R = CH3, CH3CH2, CH3(CH2)3, CH3(CH2)5, c-C3H5, C6H5, C6H5CH2, CH2CHCH2, CH2CH, C6H5CO)
Bathie, Fiona L. B.
Bowen, Chris J.
Hutton, Craig A.
O'Hair, Richard A. J.
RAPID COMMUNICATIONS IN MASS SPECTROMETRY, 2018, 32 (13) : 1045 - 1052
[42] PREPARATION AND CHARACTERIZATION OF (C6H5CH2CH2NH3)(4)BII7-CENTER-DOT-H2O, (C6H5CH2CH2NH3)(3)BIBR6 AND (C6H5CH2CH2NH3)(3)BICL6
PAPAVASSILIOU, GC
KOUTSELAS, IB
TERZIS, A
RAPTOPOULOU, CP
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1995, 50 (10): : 1566 - 1569
[43] RAMAN AND INFRARED-SPECTRA OF GASEOUS SECONDARY ALIPHATIC-AMINES [(CH3)2NH, (CH3)2ND, (C2H5)2NH AND C2H5NHCH3]
GAMER, G
WOLFF, H
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1973, A 29 (01) : 129 - 137
[44] Rate constants for the abstraction reactions RO2 + C2H6; R = H, CH3, and C2H5
Carstensen, HH
Dean, AM
PROCEEDINGS OF THE COMBUSTION INSTITUTE, 2005, 30 : 995 - 1003
[45] PREPARATION AND CHARACTERIZATION OF COBALT(III)-DIMETHYLDITHIOCARBAMATO COMPLEXES CONTAINING R2P(CH2)NPR2 (R = CH3, C6H5, N = 1, 2, 3, 4) AND PR3 (R = C2H5, C6H5) - CRYSTAL-STRUCTURE OF [CO((CH3)2NCS2)-((CH3)2PCH2P(CH3)2)2](BF4)2
KITA, M
OKUYAMA, A
KASHIWABARA, K
FUJITA, J
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1990, 63 (07) : 1994 - 2001
[46] Electrosynthesis of Rh2(dpf)4(R) where dpf = N,N′-diphenylformamidinate anion and R = CH3, C2H5, C3H7, C4H9 or C5H11
Bear, J. L.
Van Caemelbecke, E.
Ngubane, S.
Da-Riz, V.
Kadish, K. M.
DALTON TRANSACTIONS, 2011, 40 (11) : 2486 - 2490
[47] CRYSTAL AND MOLECULAR STRUCTURE OF B9C2H9(CH3)2
TSAI, CC
STREIB, WE
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1966, 88 (19) : 4513 - &
[48] STRUCTURES OF 2 NIOBIUM(IV) COMPLEXES - [N(C2H5)4]2[NBCL6] AND [P(CH3)2(C6H5)H][NBCL5(P(CH3)2(C6H5))]
COTTON, FA
DIEBOLD, MP
ROTH, WJ
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1990, 46 : 1624 - 1627
[49] Preparation and characterization of [C6H5CH2NH3]2PbI 4, [C6H5CH2CH2SC(NH2) 2]3PbI5 and [C10H7CH2NH3]PbI3 organic-inorganic hybrid compounds
Papavassiliou, G.C.
Mousdis, G.A.
Raptopoulou, C.P.
Terzis, A.
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 1999, 54 (11): : 1405 - 1409
[50] Preparation and characterization of [C6H5CH2NH3]2PbI4, [C6H5CH2CH2SC(NH2)2]3PbI5 and [C10H7CH2NH3]PbI3 organic-inorganic hybrid compounds
Papavassiliou, GC
Mousdis, GA
Raptopoulou, CP
Terzis, A
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1999, 54 (11): : 1405 - 1409

← 1 2 3 4 5 →