Pd-catalyzed Denitriative Intramolecular Mizoroki-Heck Reaction

被引：5
|
作者：
Asahara, Kitty K. [1 ]
Muto, Kei [2 ]
Yamaguchi, Junichiro [1 ]
机构：
[1] Waseda Univ, Dept Appl Chem, 513 Wasedatsurumakicho, Tokyo, Tokyo 1620041, Japan
[2] Waseda Univ, Waseda Inst Adv Study, 513 Wasedatsurumakicho, Tokyo, Tokyo 1620041, Japan
来源：
CHEMISTRY LETTERS | 2023年 / 52卷 / 04期
关键词：
Nitroarenes; Denitrative coupling; Mizoroki-Heck reaction; NITROARENES; ARYLATION; OLEFINS;
D O I：
10.1246/cl.230056
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A Pd-catalyzed denitrative intramolecular Mizoroki-Heck reaction of nitroarenes with alkenes was developed. Pd/BrettPhos is an effective catalyst for this transformation, producing 5-and 6-membered cyclic products such as indenes and benzopyrans. Since a tethered-alkene group can be introduced onto the nitroarene core through nucleophilic aromatic substitution (SNAr), the present denitrative reaction would provide a convergent synthetic method for benzo-fused cyclic compounds.
引用
收藏
页码：299 / 302
页数：4
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