Synthesis and characterization of anti-[2.2](1,4)triphenylenophane

被引：0

作者：

Yanagawa, Asuka ^{[1
]}

Inoue, Ryo ^{[1
]}

Morisaki, Yasuhiro ^{[1
]}

机构：

[1] Kwansei Gakuin Univ, Sch Biol & Environm Sci, Dept Appl Chem Environm, 1 Gakuen Uegahara, Sanda, Hyogo 6691330, Japan

来源：

CHEMISTRY LETTERS | 2024年 / 53卷 / 01期

基金：

日本学术振兴会;

关键词：

double cross-coupling; triphenylene; 2.2]paracyclophane; MACRO RINGS; DIMERS; STRATEGIES;

D O I：

10.1093/chemle/upad018

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

anti-[2.2](1,4)Triphenylenophane was synthesized by the Pd-catalyzed double cross-coupling of 4,5,12,13-tetrabromo[2.2]paracyclophane with 9,9-dimethyl-9-stannafluorene. There have been no reports on the synthesis of simple triphenylene-stacked molecules in the 75-year history of cyclophane. Its structure and properties were experimentally and theoretically studied. anti-[2.2](1,4)Triphenylenophane was synthesized by the Pd-catalyzed double cross-coupling of 4,5,12,13-tetrabromo[2.2]paracyclophane with 9,9-dimethyl-9-stannafluorene. There have been no reports on the synthesis of simple triphenylene-stacked molecules in the 75-year history of cyclophane. Its structure and properties were experimentally and theoretically studied.

引用

页数：5

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