The Dynamics of Delocalized Excitations in Organic Solar Cells with Nonfullerene Acceptors

Recently, the performance of organic solar cells has been markedly improved benefiting from the development of nonfullerene acceptors (NFAs) with acceptor???donor??? acceptor structures. Arising from the intermolecular electronic interactions between the electron donating and accepting units, intramoiety and interfacial delocalized excitations make a substantial contribution to the photocurrent generation. In this Perspective, we discuss recent studies on the excited-state dynamics responsible for the working mechanism in NFA-based organic solar cells and emphasize the dynamics of delocalized excitations in charge generation and recombination processes. The intramoiety delocalized excitations in NFAs enable charge separation without forming interfacial charge-transfer excitons first, allowing efficient photocharge generation in planar heterojunctions with reduced interfacial energy loss. We suggest a few research directions in elucidating the performance-limited processes toward the further optimization of NFA-based devices.