Ru(ii)-catalyzed oxidative coupling of sulfoxonium ylides with amines: efficient synthesis of α-ketoamides and indolo[2,1-a]isoquinolines

被引：2
|
作者：
Changmai, Sumi [1 ,2 ]
Gogoi, Tribeni [1 ,2 ]
Phukon, Jyotshna [1 ,2 ]
Das, Bipul [1 ,2 ]
Gogoi, Sanjib [1 ,2 ]
机构：
[1] North East Inst Sci & Technol, Chem Sci & Technol Div, Appl Organ Chem, CSIR, Jorhat 785006, India
[2] Acad Sci & Innovat Res AcSIR, Ghaziabad 201002, India
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2023年 / 21卷 / 15期
关键词：
INHIBITORS; ACCESS; AMIDATION; RECEPTOR; AMIDES; CARBON;
D O I：
10.1039/d3ob00187c
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The first use of sulfoxonium ylides for the synthesis of alpha-ketoamides is described via a Ru(ii)-catalyzed amidation reaction with amines. The same Ru(ii)-catalyzed reaction of sulfoxonium ylides with 2-phenylindoles provided indolo[2,1-a]isoquinolines instead of alpha-ketoamides.
引用
收藏
页码：3235 / 3244
页数：10
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