Removal of Sulphur-Containing Compounds from the Diesel Fraction by Extraction Systems Based on Coordinating Polar Solvents and Metal Salts

被引:0
|
作者
Kobotaeva, N. S. [1 ]
Skorokhodova, T. S. [1 ]
Andrienko, O. S. [2 ]
机构
[1] Russian Acad Sci, Siberian Branch, Inst Petr Chem, Tomsk, Russia
[2] Russian Acad Sci, Zuev Inst Atmospher Opt, Siberian Branch, Tomsk, Russia
来源
CHEMISTRY FOR SUSTAINABLE DEVELOPMENT | 2023年 / 31卷 / 02期
关键词
Extractive isolation of sulphur-containing compounds; polar organic solvents; metal salts;
D O I
10.15372/CSD2023454
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The process of removing sulphur-containing compounds from the diesel fraction has been carried out and investigated. The systems based on coordinating polar solvents (DMF and DMSO) and metal salts (CuCl2, CoCl2, MnCl2, Mn(TFA)2, Cu(TFA)2) were used as extractants. It has been established that the presence of metal salts in extraction systems increases the degree of removal of sulphur-containing compounds from the diesel fraction from 11 to 49 % and reduces the content of polycyclic aromatic hydrocarbons by 33 %. It is assumed that the addition of metal salts to the solvent enhances its acceptor properties, which is manifested in the enhancement of its extractability.
引用
收藏
页码:187 / 193
页数:7
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