Low-carbon steel;
Green corrosion inhibitor;
Quince extract;
Electrochemical impedance spectroscopy;
Scanning electron microscopy;
HYDROCHLORIC-ACID SOLUTION;
MILD-STEEL CORROSION;
M HCL SOLUTION;
0.5 M H2SO4;
CARBON-STEEL;
MOLECULAR-DYNAMICS;
MONTE-CARLO;
METHANOLIC EXTRACT;
FRUIT EXTRACT;
LEAF EXTRACT;
D O I:
10.1007/s12678-022-00788-6
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
The inhibitory performance of quince extract (QE) on the corrosion and electrochemical properties of low-carbon steel in 1 molar hydrochloric acid was studied by electrochemical methods and weight loss measurement. The chemical compounds contained in quince that offer substantial corrosion inhibition impacts (e.g., amino acids and flavonoids) were examined by Fourier-transform infrared spectroscopy and ultraviolet. Polarization tests and electrochemical impedance spectroscopy results showed that increasing the concentration of the extract in the range of 200-1200 ppm increased its inhibition efficiency. The highest inhibition efficiency of the extract based on polarization and EIS results was respectively 95% and 93.0%, both observed at a concentration of 1200 ppm. Based on the results, quince extract was considered as a mixed-type corrosion inhibitor. Scanning electron microscopy and atomic force microscopy of the surface of steel specimens immersed in 1 M HCl without and with 200-1200 ppm of the inhibitor showed the effectiveness of quince extract in preventing corrosion.
机构:
Department of Chemical Engineering, College of Engineering, University of Diyala, Baquba City, Diyala
Department of Engineering/Chemical Engineering, College of Applied Sciences, Suhar, SuharDepartment of Chemical Engineering, College of Engineering, University of Diyala, Baquba City, Diyala
Khadom A.A.
Abod B.M.
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机构:
Technical Engineering College, Middle Technical University, BaghdadDepartment of Chemical Engineering, College of Engineering, University of Diyala, Baquba City, Diyala
Abod B.M.
Mahood H.B.
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机构:
Department of Engineering/Chemical Engineering, College of Applied Sciences, Suhar, Suhar
University of Misan, MisanDepartment of Chemical Engineering, College of Engineering, University of Diyala, Baquba City, Diyala
Mahood H.B.
Kadhum A.A.H.
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机构:
Department of Chemical and Process Engineering, Faculty of Engineering and Built Environment, Universiti Kebangsaan Malaysia, Bangi, 43600, SelangorDepartment of Chemical Engineering, College of Engineering, University of Diyala, Baquba City, Diyala
机构:
Laboratory of Bioactive Molecules and Applications, Larbi Tebessi University, TebessaLaboratory of Bioactive Molecules and Applications, Larbi Tebessi University, Tebessa
Souhir E.
Brahim H.
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Laboratory of Bioactive Molecules and Applications, Larbi Tebessi University, TebessaLaboratory of Bioactive Molecules and Applications, Larbi Tebessi University, Tebessa
Brahim H.
Samah H.
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机构:
Laboratory of Computational Chemistry and Nanostructure, University May 08, GuelmaLaboratory of Bioactive Molecules and Applications, Larbi Tebessi University, Tebessa
机构:
Chongqing Univ Arts & Sci, Sch Mat & Chem Engn, Yongchuan 402160, Peoples R China
Pingdingshan Univ, Sch Chem & Environm Engn, Pingdingshan 467099, Peoples R ChinaChongqing Univ Arts & Sci, Sch Mat & Chem Engn, Yongchuan 402160, Peoples R China
Feng, Yangyang
He, Jiahong
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Chongqing Univ Arts & Sci, Sch Mat & Chem Engn, Yongchuan 402160, Peoples R ChinaChongqing Univ Arts & Sci, Sch Mat & Chem Engn, Yongchuan 402160, Peoples R China
He, Jiahong
Zhan, Youli
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Chongqing Univ Arts & Sci, Sch Mat & Chem Engn, Yongchuan 402160, Peoples R ChinaChongqing Univ Arts & Sci, Sch Mat & Chem Engn, Yongchuan 402160, Peoples R China
Zhan, Youli
An, Jibin
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Chongqing Univ Arts & Sci, Sch Mat & Chem Engn, Yongchuan 402160, Peoples R ChinaChongqing Univ Arts & Sci, Sch Mat & Chem Engn, Yongchuan 402160, Peoples R China
An, Jibin
Tan, Bochuan
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机构:
Chongqing Univ, Sch Chem & Chem Engn, Chongqing 400044, Peoples R ChinaChongqing Univ Arts & Sci, Sch Mat & Chem Engn, Yongchuan 402160, Peoples R China