Recent Advances in Reactions Involving Carbon Dioxide Radical Anion

被引：53
|
作者：
Xiao, Wei [1 ,2 ]
Zhang, Jun [1 ,2 ]
Wu, Jie [1 ,2 ,3 ]
机构：
[1] Taizhou Univ, Sch Pharmaceut & Chem Engn, Taizhou 318000, Peoples R China
[2] Taizhou Univ, Inst Adv Studies, Taizhou 318000, Peoples R China
[3] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
来源：
ACS CATALYSIS | 2023年 / 13卷 / 24期
基金：
中国国家自然科学基金;
关键词：
carbon dioxide radical anion; single-electron-reductant; carboxylation; photocatalysis; electrocatalysis; CATALYZED SELECTIVE CARBOXYLATION; FORMATE SALTS; UNACTIVATED ALKENES; HYDROCARBOXYLATION; REDUCTION; CO2; GENERATION; BONDS; ACTIVATION; STYRENES;
D O I：
10.1021/acscatal.3c04125
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Carbon dioxide radical anion (CO2 center dot-) is a highly reactive nucleophilic radical species that has recently emerged in organic chemistry as a strong single electron donor (reductant) and as a reactant for the synthesis of carboxylic acids. In general, CO2 center dot- can be generated by either direct reduction of CO2 or HAT of formate salts. Achievements in reactions involving CO2 center dot- have been witnessed in recent years. This Review summarizes the recent advances in reactions involving CO2 center dot- by highlighting some challenges and identifying potential areas of improvement, which may offer inspiration for future studies.
引用
收藏
页码：15991 / 16011
页数：21
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