Electric field gradients at rubidium sites in rubidium uranyl nitrate and quadrupole moments of 85Rb and 87Rb

被引：0

作者：

Park, Sejun ^{[1
]}

Surbella, Robert G., III ^{[2
]}

Sinkov, Sergey I. ^{[3
]}

Philips, Adam B. ^{[4
]}

Autschbach, Jochen ^{[4
]}

Cho, Herman ^{[1
]}

机构：

[1] Pacific Northwest Natl Lab, Phys & Computat Sci Directorate, Richland, WA 99354 USA

[2] Pacific Northwest Natl Lab, Natl Secur Directorate, Richland, WA 99354 USA

[3] Pacific Northwest Natl Lab, Energy & Environm Directorate, Richland, WA 99354 USA

[4] SUNY Buffalo, Dept Chem, Buffalo, NY 14260 USA

来源：

CHEMICAL PHYSICS | 2024年 / 576卷

关键词：

Actinyl electronic structure; Electric field gradient; Rubidium isotope nuclear quadrupole moments; NUCLEAR-MAGNETIC-RESONANCE; SOLID-STATE; SPIN-ORBIT; MOSSBAUER; APPROXIMATION; NMR;

D O I：

10.1016/j.chemphys.2023.112094

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The electronic structure along the axial direction of the uranyl ion in rubidium uranyl nitrate (RbUO2(NO3)(3)) has been probed by nuclear quadrupole resonance and nuclear magnetic resonance measurements of Rb-85 and Rb-87 quadrupole couplings. The parameter of interest in these experiments is the electric field gradient at the Rb sites, which may be compared with values computed by various theoretical approaches. From this analysis a refinement of the ratio of the quadrupole moments of Rb-85 and Rb-87 has also been obtained.

引用

页数：6

共 50 条

[31] Isotope study of the nonlinear pressure shifts of 85Rb and 87Rb hyperfine resonances in Ar, Kr, and Xe buffer gases
McGuyer, B. H.
JOURNAL OF CHEMICAL PHYSICS, 2023, 158 (14):
[32] Nonlinear magneto-optical resonances at D1 excitation of 85Rb and 87Rb in an extremely thin cell
Auzinsh, M.
Ferber, R.
Gahbauer, F.
Jarmola, A.
Kalvans, L.
Papoyan, A.
Sarkisyan, D.
PHYSICAL REVIEW A, 2010, 81 (03):
[33] Comments on the paper "Quantum defect and Rydberg energy level calculations for 85Rb and 87Rb by Weakest Bound Electron Potential Model"
Siddiq, Rizwana
Raza, Salman
Rehman, Shafiq Ur
Rajput, Ahmed Ali
Zahid, M. Mustaqeem
Uddin, Zaheer
CHINESE JOURNAL OF PHYSICS, 2024, 91 : 512 - 524
[34] Absolute frequency measurements of the D1 lines in 39K, 85Rb, and 87Rb with ∼0.1 ppb uncertainty
Banerjee, A
Das, D
Natarajan, V
EUROPHYSICS LETTERS, 2004, 65 (02): : 172 - 178
[35] Deeply bound (24DJ+5S1/2) 87Rb and 85Rb molecules for eight spin couplings
MacLennan, Jamie L.
Chen, Yun-Jhih
Raithel, Georg
PHYSICAL REVIEW A, 2019, 99 (03)
[36] Some anomalous phenomena of 87Rb atoms fluorescence in a quadrupole magnetic field
Long, Q
Zhou, SY
Wang, YZ
FRONTIERS OF LASER PHYSICS AND QUANTUM OPTICS, 2000, : 533 - 535
[37] Suppression of Coriolis error in weak equivalence principle test using 85Rb–87Rb dual-species atom interferometer
段维涛
何川
闫思彤
冀宇航
周林
陈曦
王谨
詹明生
Chinese Physics B, 2020, (07) : 96 - 103
[38] Determination of the hyperfine structure constants of the 87Rb and 85Rb 4D5/2 state and the isotope hyperfine anomaly
Wang, Jie
Liu, Huifeng
Yang, Guang
Yang, Baodong
Wang, Junmin
PHYSICAL REVIEW A, 2014, 90 (05):
[39] Effects of ischemia on intracellular rubidium in pig and rat hearts:: 87Rb NMR imaging and spectroscopic study
Kupriyanov, VV
Xiang, B
Sun, J
Jilkina, O
Dai, G
Deslauriers, R
MAGNETIC RESONANCE IN MEDICINE, 2000, 44 (02) : 193 - 200
[40] Solid-state 87Rb NMR signatures for rubidium cations bound to a G-quadruplex
Ida, R
Wu, G
CHEMICAL COMMUNICATIONS, 2005, (34) : 4294 - 4296

← 1 2 3 4 5 →